trans,trans-(C₆F₅)(Ph₂P(CH₂)7CH=CH₂)2Pt(C₂)4Pt(Ph₂P(CH₂)7CHCH₂)2(C₆F₅)

Base Information

• Chemical Name: trans,trans-(C₆F₅)(Ph₂P(CH₂)7CH=CH₂)2Pt(C₂)4Pt(Ph₂P(CH₂)7CHCH₂)2(C₆F₅)
• CAS No.: 945679-56-1
• Molecular Formula: C₁₀₄H₁₀₈F₁₀P₄Pt₂
• Molecular Weight: 2062.04
• Mol file: 945679-56-1.mol

Synonyms:trans,trans-(C₆F₅)(Ph₂P(CH₂)7CH=CH₂)2Pt(C₂)4Pt(Ph₂P(CH₂)7CHCH₂)2(C₆F₅)

Chemical Property of trans,trans-(C₆F₅)(Ph₂P(CH₂)7CH=CH₂)2Pt(C₂)4Pt(Ph₂P(CH₂)7CHCH₂)2(C₆F₅)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans,trans-(C₆F₅)(Ph₂P(CH₂)7CH=CH₂)2Pt(C₂)4Pt(Ph₂P(CH₂)7CHCH₂)2(C₆F₅)

There total 1 articles about trans,trans-(C₆F₅)(Ph₂P(CH₂)7CH=CH₂)2Pt(C₂)4Pt(Ph₂P(CH₂)7CHCH₂)2(C₆F₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

trans-(C6F5)(Ph2P(CH2)7CH=CH2)2Pt(C2)2H (945679-64-1) → trans,trans-(C6F5)(Ph2P(CH2)7CH=CH2)2Pt(C2)4Pt(Ph2P(CH2)7CHCH2)2(C6F5) (945679-56-1)

Guidance literature:

With catalyst: CuI/N,N,N',N'-tetramethylethylenediamine; O₂; In acetone; O2, acetone, catalyst: CuCl/TMEDA; as oil;

DOI:10.1021/ja071612n

Reference yield: 48.0%

trans,trans-(C6F5)(Ph2P(CH2)7CH=CH2)2Pt(C2)4Pt(Ph2P(CH2)7CHCH2)2(C6F5) (945679-56-1) + hydrogen (1333-74-0) → trans,trans-(C6F5)(Ph2P)2(CH2)16Pt(C2)4Pt(CH2)16(Ph2P)2(C6F5) (945679-49-2,945679-58-3) + trans,trans-(C6F5)(Ph2P-(CH2)16PPh2)Pt-(C2)4Pt-(Ph2P(CH2)16Ph2P-)(C6F5) (945679-58-3,945679-49-2)

Guidance literature:

With catalyst: Pd/C; Grubbs catalyst first generation; In ethanol; 1,2-dichloro-ethane; 1. 5-7% Crubbs'catalyst, Pd-complex and CH2Cl2, reflux for 5 h, chromd. on alumina column (CH2Cl2), rotary evapd.; 2. the crude mixt., 10% Pd/C,ClCH2CH2Cl2, ethanol, 1 atm. of H2, stirred for 14 d; the solvent was rotary evapd., the CH2Cl2-extract was passed through an alumina column (CH2Cl2), the solvent was removed by oil pump vac., chromy. on silica gel column (80:20 v/v hexanes/CH2Cl2); elem. anal.;

DOI:10.1021/ja071612n

upstream raw materials:

trans-(C₆F₅)(Ph₂P(CH₂)7CH=CH₂)2Pt(C₂)2H

Downstream raw materials:

trans,trans-(C₆F₅)(Ph₂P)2(CH₂)16Pt(C₂)4Pt(CH₂)16(Ph₂P)2(C₆F₅)

trans,trans-(C₆F₅)(Ph₂P-(CH₂)16PPh₂)Pt-(C₂)4Pt-(Ph₂P(CH₂)16Ph₂P-)(C₆F₅)