Technology Process of 2,4,6-tri-tert-butylbenzeneselenol
There total 1 articles about 2,4,6-tri-tert-butylbenzeneselenol which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
In
benzene-d6;
Product distribution;
Ambient temperature;
various reactant ratio, other temperature;
DOI:10.1021/jo982514a
- Guidance literature:
-
In
light petroleum;
byproducts: THF, HN(SiMe3)2; inert atmosphere; addn. of Mn-complex soln. to 2 equiv. of ligand (-78°C, pptn.), stirring (10 min), slow warming to room temp., stirring (1 h); filtration, washing (light petroleum), drying (vac.); can be recrystallized (MePh); elem. anal.;
DOI:10.1039/DT9950001645
- Guidance literature:
-
With
n-butyl lithium;
In
toluene;
slow addn. of a hexane soln. of n-BuLi to a soln. of HSe(2,4,6-t-Bu3C6H2) in toluene at room temp.; stirring for 2 h; dropwise addn. of the soln. to GaCl3 in toluene at room temp.; stirring for 18 h; all steps were performed under N2 atm.;; filtration through Celite; concg. under reduced pressure; crystn. on storage at room temp.;;
