μ-[15,15'-bis(3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl)-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),κN(24')]dizinc

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Chemical Name:μ-[15,15'-bis(3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl)-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),κN(24')]dizinc
CAS No.:495413-32-6
Molecular Formula:C₁₂₀H₁₂₆N₈O₈Zn₂
Molecular Weight:1939.15
Hs Code.:

μ-[15,15'-bis(3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl)-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),κN(24')]dizinc

Synonyms:μ-[15,15'-bis(3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl)-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),κN(24')]dizinc

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Chemical Property of μ-[15,15'-bis(3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl)-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),κN(24')]dizinc

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Technology Process of μ-[15,15'-bis(3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl)-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),κN(24')]dizinc

There total 2 articles about μ-[15,15'-bis(3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl)-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),κN(24')]dizinc which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 495413-29-1
(Zn(C₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C(C₆H₄CH₂OSi(CH₃)2C(CH₃)3)C₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C))2

: 36239-09-5
ethyl chlorocarbonylacetate

: 495413-32-6
μ-[15,15'-bis(3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl)-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),κN(24')]dizinc

Guidance literature:: With tetrabutyl ammonium fluoride; triethylamine; In dichloromethane; mixt. of Zn-complex, (C4H9)4NF reacted in CH2Cl2 at rt for 3 h; soln. ofC2H5OOCCH2COCl, (C2H5)3N in CH2Cl2 added; mixt reacted for 1.5 h at roo m temp.;
DOI:10.1039/b206624f

Reference yield: 67.0%

: 866321-88-2
μ-[15,15'-bis[3-(hydroxymethyl)phenyl]-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

: 36239-09-5
ethyl chlorocarbonylacetate

: 495413-32-6
μ-[15,15'-bis(3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl)-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),κN(24')]dizinc

Guidance literature:: With triethyl amine; In dichloromethane; N2 atm.; ClCOCH2CO3C2H5 was added to a soln. of complex and triethylamine in dry CH2Cl2 at 0°C, the mixt. was stirred for 30 min at 0°C, then for 1 h at 25°C; CHCl3 was added followed by H2O, the organic layer was washed with H2O, satd. aq. NaCl, dried (Na2SO4), evapd. in vac.; flash chromy. (silica gel; cyclohexane/CH2Cl2 1:1, 1% v/v (C2H5)3N), pptn. from methanol by addn. dropwise of H2O;
DOI:10.1002/hlca.200590144