μ-[15,15'-bis[3-(hydroxymethyl)phenyl]-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

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Chemical Name:μ-[15,15'-bis[3-(hydroxymethyl)phenyl]-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)
CAS No.:866321-88-2
Molecular Formula:C₁₁₀H₁₁₄N₈O₂Zn₂
Molecular Weight:1710.95
Hs Code.:

μ-[15,15'-bis[3-(hydroxymethyl)phenyl]-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

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Chemical Property of μ-[15,15'-bis[3-(hydroxymethyl)phenyl]-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

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Technology Process of μ-[15,15'-bis[3-(hydroxymethyl)phenyl]-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

There total 1 articles about μ-[15,15'-bis[3-(hydroxymethyl)phenyl]-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 495413-29-1
(Zn(C₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C(C₆H₄CH₂OSi(CH₃)2C(CH₃)3)C₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C))2

: 7732-18-5
water

: 866321-88-2
μ-[15,15'-bis[3-(hydroxymethyl)phenyl]-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

Guidance literature:: With (C₄H₉)4NF; In tetrahydrofuran; N2 atm.; several drops of 1 M soln. of (C4H9)4NF in THF were added at 0°C to a soln. of complex in THF, the mixt. was stirred for 30 min at 0°C and 1 h at 25°C; CHCl3 was added followed by H2O, the organic layer was washed with H2O, satd. aq. NaCl, dried (Na2SO4), evapd. in vac.; flash chromy. (silica gel; cyclohexane/CH2Cl2 1:1, 1% v/v (C2H5)3N), pptn. from CHCl3 by addn. of methanol/H2O 9:1;
DOI:10.1002/hlca.200590144

Reference yield: 67.0%

: 866321-88-2
μ-[15,15'-bis[3-(hydroxymethyl)phenyl]-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

: 36239-09-5
ethyl chlorocarbonylacetate

: 495413-32-6
μ-[15,15'-bis(3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl)-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),κN(24')]dizinc

Guidance literature:: With triethyl amine; In dichloromethane; N2 atm.; ClCOCH2CO3C2H5 was added to a soln. of complex and triethylamine in dry CH2Cl2 at 0°C, the mixt. was stirred for 30 min at 0°C, then for 1 h at 25°C; CHCl3 was added followed by H2O, the organic layer was washed with H2O, satd. aq. NaCl, dried (Na2SO4), evapd. in vac.; flash chromy. (silica gel; cyclohexane/CH2Cl2 1:1, 1% v/v (C2H5)3N), pptn. from methanol by addn. dropwise of H2O;
DOI:10.1002/hlca.200590144