13-benzoxy-(2R,6S,10S)-2,6,10-trimethyl-1-tridecanol

Base Information

Chemical Name:13-benzoxy-(2R,6S,10S)-2,6,10-trimethyl-1-tridecanol
CAS No.:1443233-29-1
Molecular Formula:C₂₃H₄₀O₂
Molecular Weight:348.569
Hs Code.:

Synonyms:13-benzoxy-(2R,6S,10S)-2,6,10-trimethyl-1-tridecanol

Suppliers and Price of 13-benzoxy-(2R,6S,10S)-2,6,10-trimethyl-1-tridecanol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 13-benzoxy-(2R,6S,10S)-2,6,10-trimethyl-1-tridecanol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 13-benzoxy-(2R,6S,10S)-2,6,10-trimethyl-1-tridecanol

There total 15 articles about 13-benzoxy-(2R,6S,10S)-2,6,10-trimethyl-1-tridecanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 13-benzoxy-(2R,6S,10R)-2,6,10-trimethyl-8-(Z/E)-8-tridecenol-1

: 1443233-29-1
13-benzoxy-(2R,6S,10S)-2,6,10-trimethyl-1-tridecanol

Guidance literature:: With oxygen; copper(II) sulfate; hydrazine; In ethanol; at 70 ℃; for 15h;
DOI:10.1021/jo4006602

Reference yield:

: 186641-76-9
(2R)-1-(tert-butyldiphenylsilyloxy)-3-cyano-2-methylpropane

: 1443233-29-1
13-benzoxy-(2R,6S,10S)-2,6,10-trimethyl-1-tridecanol

Guidance literature:: Multi-step reaction with 11 steps

1.1: diisobutylaluminium hydride

2.1: lithium hexamethyldisilazane / tetrahydrofuran / -78 - 20 °C / Inert atmosphere

3.1: tetrahydrofuran / 20 °C / Inert atmosphere

4.1: sodium peroxoborate tetrahydrate / tetrahydrofuran; water / 2 h / 20 °C / Inert atmosphere

5.1: sodium hydride / tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere

5.2: 20 °C / Inert atmosphere

6.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 20 °C

7.1: triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran / 1 h / 0 - 20 °C / Inert atmosphere

8.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0 - 20 °C

9.1: lithium hexamethyldisilazane / tetrahydrofuran / -78 - 20 °C / Inert atmosphere

10.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 20 °C

11.1: hydrazine; copper(II) sulfate; oxygen / ethanol / 15 h / 70 °C

With sodium peroxoborate tetrahydrate; tetrabutyl ammonium fluoride; oxygen; sodium hydride; diisobutylaluminium hydride; copper(II) sulfate; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; lithium hexamethyldisilazane; hydrazine; diethylazodicarboxylate; In tetrahydrofuran; ethanol; dichloromethane; water; 2.1: |Julia-Kocienski Olefination / 9.1: |Julia-Kocienski Olefination;
DOI:10.1021/jo4006602

Reference yield:

: 186641-79-2
(R)-4-((tert-Butyldiphenylsilyl)oxy)-3-methylbutanal

: 1443233-29-1
13-benzoxy-(2R,6S,10S)-2,6,10-trimethyl-1-tridecanol

Guidance literature:: Multi-step reaction with 10 steps

1.1: lithium hexamethyldisilazane / tetrahydrofuran / -78 - 20 °C / Inert atmosphere

2.1: tetrahydrofuran / 20 °C / Inert atmosphere

3.1: sodium peroxoborate tetrahydrate / tetrahydrofuran; water / 2 h / 20 °C / Inert atmosphere

4.1: sodium hydride / tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere

4.2: 20 °C / Inert atmosphere

5.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 20 °C

6.1: triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran / 1 h / 0 - 20 °C / Inert atmosphere

7.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0 - 20 °C

8.1: lithium hexamethyldisilazane / tetrahydrofuran / -78 - 20 °C / Inert atmosphere

9.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 20 °C

10.1: hydrazine; copper(II) sulfate; oxygen / ethanol / 15 h / 70 °C

With sodium peroxoborate tetrahydrate; tetrabutyl ammonium fluoride; oxygen; sodium hydride; copper(II) sulfate; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; lithium hexamethyldisilazane; hydrazine; diethylazodicarboxylate; In tetrahydrofuran; ethanol; dichloromethane; water; 1.1: |Julia-Kocienski Olefination / 8.1: |Julia-Kocienski Olefination;
DOI:10.1021/jo4006602