5-[13-benzoxy-(2R,6R,10S)-2,6,10-trimethyl-1-tridecylsulfanyl]-1-phenyl-1H-tetrazole

Base Information

Chemical Name:5-[13-benzoxy-(2R,6R,10S)-2,6,10-trimethyl-1-tridecylsulfanyl]-1-phenyl-1H-tetrazole
CAS No.:1443233-30-4
Molecular Formula:C₃₀H₄₄N₄OS
Molecular Weight:508.772
Hs Code.:

Synonyms:5-[13-benzoxy-(2R,6R,10S)-2,6,10-trimethyl-1-tridecylsulfanyl]-1-phenyl-1H-tetrazole

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Chemical Property of 5-[13-benzoxy-(2R,6R,10S)-2,6,10-trimethyl-1-tridecylsulfanyl]-1-phenyl-1H-tetrazole

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Technology Process of 5-[13-benzoxy-(2R,6R,10S)-2,6,10-trimethyl-1-tridecylsulfanyl]-1-phenyl-1H-tetrazole

There total 16 articles about 5-[13-benzoxy-(2R,6R,10S)-2,6,10-trimethyl-1-tridecylsulfanyl]-1-phenyl-1H-tetrazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1443233-29-1
13-benzoxy-(2R,6S,10S)-2,6,10-trimethyl-1-tridecanol

: 86-93-1
1-Phenyl-1H-tetrazole-5-thiol

: 1443233-30-4
5-[13-benzoxy-(2R,6R,10S)-2,6,10-trimethyl-1-tridecylsulfanyl]-1-phenyl-1H-tetrazole

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; at 0 - 20 ℃; for 0.5h; Inert atmosphere;
DOI:10.1021/jo4006602

Reference yield:

: 186641-76-9
(2R)-1-(tert-butyldiphenylsilyloxy)-3-cyano-2-methylpropane

: 1443233-30-4
5-[13-benzoxy-(2R,6R,10S)-2,6,10-trimethyl-1-tridecylsulfanyl]-1-phenyl-1H-tetrazole

Guidance literature:: Multi-step reaction with 12 steps

1.1: diisobutylaluminium hydride

2.1: lithium hexamethyldisilazane / tetrahydrofuran / -78 - 20 °C / Inert atmosphere

3.1: tetrahydrofuran / 20 °C / Inert atmosphere

4.1: sodium peroxoborate tetrahydrate / tetrahydrofuran; water / 2 h / 20 °C / Inert atmosphere

5.1: sodium hydride / tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere

5.2: 20 °C / Inert atmosphere

6.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 20 °C

7.1: triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran / 1 h / 0 - 20 °C / Inert atmosphere

8.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0 - 20 °C

9.1: lithium hexamethyldisilazane / tetrahydrofuran / -78 - 20 °C / Inert atmosphere

10.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 20 °C

11.1: hydrazine; copper(II) sulfate; oxygen / ethanol / 15 h / 70 °C

12.1: triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran / 0.5 h / 0 - 20 °C / Inert atmosphere

With sodium peroxoborate tetrahydrate; tetrabutyl ammonium fluoride; oxygen; sodium hydride; diisobutylaluminium hydride; copper(II) sulfate; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; lithium hexamethyldisilazane; hydrazine; diethylazodicarboxylate; In tetrahydrofuran; ethanol; dichloromethane; water; 2.1: |Julia-Kocienski Olefination / 9.1: |Julia-Kocienski Olefination;
DOI:10.1021/jo4006602

Reference yield:

: 186641-79-2
(R)-4-((tert-Butyldiphenylsilyl)oxy)-3-methylbutanal

: 1443233-30-4
5-[13-benzoxy-(2R,6R,10S)-2,6,10-trimethyl-1-tridecylsulfanyl]-1-phenyl-1H-tetrazole

Guidance literature:: Multi-step reaction with 11 steps

1.1: lithium hexamethyldisilazane / tetrahydrofuran / -78 - 20 °C / Inert atmosphere

2.1: tetrahydrofuran / 20 °C / Inert atmosphere

3.1: sodium peroxoborate tetrahydrate / tetrahydrofuran; water / 2 h / 20 °C / Inert atmosphere

4.1: sodium hydride / tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere

4.2: 20 °C / Inert atmosphere

5.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 20 °C

6.1: triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran / 1 h / 0 - 20 °C / Inert atmosphere

7.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0 - 20 °C

8.1: lithium hexamethyldisilazane / tetrahydrofuran / -78 - 20 °C / Inert atmosphere

9.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 20 °C

10.1: hydrazine; copper(II) sulfate; oxygen / ethanol / 15 h / 70 °C

11.1: triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran / 0.5 h / 0 - 20 °C / Inert atmosphere

With sodium peroxoborate tetrahydrate; tetrabutyl ammonium fluoride; oxygen; sodium hydride; copper(II) sulfate; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; lithium hexamethyldisilazane; hydrazine; diethylazodicarboxylate; In tetrahydrofuran; ethanol; dichloromethane; water; 1.1: |Julia-Kocienski Olefination / 8.1: |Julia-Kocienski Olefination;
DOI:10.1021/jo4006602