phenyliodoniomethanesulfonate

Base Information

• Chemical Name: phenyliodoniomethanesulfonate
• CAS No.: 118163-37-4
• Molecular Formula: C₁₁H₁₁IO₇S
• Molecular Weight: 414.175
• Mol file: 118163-37-4.mol

Synonyms:phenyliodoniomethanesulfonate

Chemical Property of phenyliodoniomethanesulfonate

Chemical Property:

Purity/Quality:

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Technology Process of phenyliodoniomethanesulfonate

There total 1 articles about phenyliodoniomethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(methoxycarbonyl)(phenyliodinio)methanide (145838-86-4) → phenyliodoniomethanesulfonate (118163-37-4)

Guidance literature:

With sulfur trioxide; In dichloromethane; at -78 ℃; Yield given;

Reference yield: 15.0%

1-hexene (592-41-6,25067-06-5) + phenyliodoniomethanesulfonate (118163-37-4) → iodobenzene (591-50-4) + Tetramethyl ethylenetetracarboxylate (1733-15-9) + 5-butyl-3,3-(methoxycarbonyl)-1,2-oxathiole 2,2-dioxide (118163-38-5) + 2,2,5,5-tetraoxy-3,3,6,6-tetramethoxycarbonyl-1,4-dioxa-2,5-dithiane (109629-28-9)

Guidance literature:

In dichloromethane; at 0 ℃;

Reference yield:

phenyliodoniomethanesulfonate (118163-37-4) + cyclohexene (110-83-8) → Tetramethyl ethylenetetracarboxylate (1733-15-9) + dimethyl 2-(cyclohex-2-en-1-yl)malonate (34939-28-1) + 4-cyclohexene (115740-69-7) + 2,2,5,5-tetraoxy-3,3,6,6-tetramethoxycarbonyl-1,4-dioxa-2,5-dithiane (109629-28-9)

Guidance literature:

In dichloromethane; at 20 ℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

upstream raw materials:

bis(methoxycarbonyl)(phenyliodinio)methanide

Downstream raw materials:

iodobenzene

Tetramethyl ethylenetetracarboxylate

5-butyl-3,3-(methoxycarbonyl)-1,2-oxathiole 2,2-dioxide

2,2,5,5-tetraoxy-3,3,6,6-tetramethoxycarbonyl-1,4-dioxa-2,5-dithiane