115740-69-7Relevant academic research and scientific papers
Deprotonation of the adducts of β-dicarbonyl anions and [(η4-diene)Co(CO)3]BF4
Barinelli, Lucio S.,Li, Zhong,Nicholas, Kenneth M.
, p. 2474 - 2476 (2008/10/08)
The adducts of stabilized enolates and [(η4-1,3-butadiene)Co(CO)3]BF4 (1) and [(η4-1,3-cyclohexadiene)Co(CO)3]BF4 (2) undergo deprotonation and subsequent reactions to form either hydrofurans, cyclopropanes, or α,β,γ,δ-diunsaturated dicarbonyl derivatives depending upon the reacting complex and the β-dicarbonyl component. All of the observed reactions are strongly promoted by HMPA.
