Diphenylphosphino amine

Base Information

• Chemical Name: Diphenylphosphino amine
• CAS No.: 17157-61-8
• Molecular Formula: C₁₂H₁₂NP
• Molecular Weight: 201.208
• DSSTox Substance ID: DTXSID301307466
• Nikkaji Number: J2.150.259F
• Mol file: 17157-61-8.mol

Synonyms:diphenylphosphino amine;P,P-Diphenylphosphinous amide;SCHEMBL14948634;DTXSID301307466;17157-61-8

Chemical Property of Diphenylphosphino amine

Chemical Property:

• XLogP3: 2.3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 201.070736385
• Heavy Atom Count: 14
• Complexity: 142

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)N

Technology Process of Diphenylphosphino amine

There total 3 articles about Diphenylphosphino amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

piperazine-1,4-diylbis(diphenylphosphine)oxide → 3-ethyl-1H-pyrrole (1551-16-2) + 2-Methylpyrazine (109-08-0) + 4,4'-bipyridine (553-26-4) + 2-methylimidazole (693-98-1) + trans-2-Butene (624-64-6) + carbon dioxide (124-38-9,18923-20-1) + N-methylaniline (100-61-8) + diphenylphosphane (829-85-6) + diphenyl(methyl)phosphine (1486-28-8) + bis(diphenylphosphino)amine (17157-61-8)

Guidance literature:

at 600 ℃;

DOI:10.1039/c7ra09868e

Reference yield:

chloro-diphenylphosphine (1079-66-9,74391-44-9) → bis(diphenylphosphino)amine (17157-61-8)

Guidance literature:

With ammonia; In dichloromethane; at -45 - 20 ℃; for 1.25h; Inert atmosphere;

DOI:10.1016/j.tet.2019.04.029

Reference yield:

→ bis(diphenylphosphino)amine (17157-61-8)

Guidance literature:

Triphenylphosphin, KNH2, 130grad, Autoklav;

upstream raw materials:

chloro-diphenylphosphine

Downstream raw materials:

diphenylphosphinamide

P,P-diphenylphosphinothioic amide