2-(3-(4-fluorophenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Base Information

Chemical Name:2-(3-(4-fluorophenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS No.:1294009-16-7
Molecular Formula:C₁₅H₂₀BFO₂
Molecular Weight:262.132
Hs Code.:

Synonyms:2-(3-(4-fluorophenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-(3-(4-fluorophenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

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Technology Process of 2-(3-(4-fluorophenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

There total 6 articles about 2-(3-(4-fluorophenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 3798-61-6,179249-16-2
1-(4-fluorophenyl)prop-2-yn-1-ol

: 73183-34-3
bis(pinacol)diborane

: 1294009-16-7
2-(3-(4-fluorophenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With titanium(IV) isopropylate; copper diacetate; isopropyl alcohol; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; In toluene; at 60 ℃; for 18h; regioselective reaction; Inert atmosphere; Glovebox;
DOI:10.1021/acs.orglett.7b03294

Reference yield: 74.0%

: 1429766-96-0
2-((2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)sulfonyl)pyridine

: 352-13-6
4-flourophenylmagnesium bromide

: 1294009-16-7
2-(3-(4-fluorophenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With copper(II) bis(trifluoromethanesulfonate); In dichloromethane; N,N-dimethyl-formamide; at 20 ℃; for 0.5h; regioselective reaction; Inert atmosphere;
DOI:10.1021/ol4007663

Reference yield:

: 459-57-4
4-fluorobenzaldehyde

: 1294009-16-7
2-(3-(4-fluorophenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran / 0 - 20 °C / Inert atmosphere

2: copper diacetate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; titanium(IV) isopropylate; isopropyl alcohol / toluene / 18 h / 60 °C / Inert atmosphere; Glovebox

With titanium(IV) isopropylate; copper diacetate; isopropyl alcohol; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; In tetrahydrofuran; toluene;
DOI:10.1021/acs.orglett.7b03294