DIMETHYLSILYL (T-BUTYLAMIDO)CYCLOPENTADIENYL ZIRCONIUM DICHLORIDE

Base Information

Chemical Name:DIMETHYLSILYL (T-BUTYLAMIDO)CYCLOPENTADIENYL ZIRCONIUM DICHLORIDE
CAS No.:184899-34-1
Molecular Formula:C₁₁H₁₉Cl₂NSiZr
Molecular Weight:355.494
Hs Code.:
Mol file:184899-34-1.mol

Synonyms:DIMETHYLSILYL (TERT-BUTYLAMIDO)CYCLOPENTADIENYL ZIRCONIUM DICHLORIDE;DIMETHYLSILYL (T-BUTYLAMIDO)CYCLOPENTADIENYL ZIRCONIUM DICHLORIDE

Suppliers and Price of DIMETHYLSILYL (T-BUTYLAMIDO)CYCLOPENTADIENYL ZIRCONIUM DICHLORIDE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
DIMETHYLSILYL (T-BUTYLAMIDO)CYCLOPENTADIENYL ZIRCONIUM DICHLORIDE 95.00%
5MG
$ 496.76

Total 5 raw suppliers

Chemical Property of DIMETHYLSILYL (T-BUTYLAMIDO)CYCLOPENTADIENYL ZIRCONIUM DICHLORIDE

Chemical Property:

PSA：3.24000
LogP:4.21330

Purity/Quality:

98% ^*data from raw suppliers

DIMETHYLSILYL (T-BUTYLAMIDO)CYCLOPENTADIENYL ZIRCONIUM DICHLORIDE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of DIMETHYLSILYL (T-BUTYLAMIDO)CYCLOPENTADIENYL ZIRCONIUM DICHLORIDE

There total 4 articles about DIMETHYLSILYL (T-BUTYLAMIDO)CYCLOPENTADIENYL ZIRCONIUM DICHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 75-77-4
chloro-trimethyl-silane

: 174872-32-3
(tert-butyl-N-SiMe₂-cyclopentadienyl)Zr(NMe₂)2

: 184899-34-1
(η(5):η(1)-C5H4SiMe2N(t)Bu)ZrCl2

Guidance literature:: In toluene; Zr-complex was placed in flask, toluene and SiMe3Cl were added, heated at 65°C overnight; solvent was removed, washed with pentane; elem. anal.;
DOI:10.1021/ic040001i

Reference yield: 56.0%

: ((C₅H₄Si(CH₃)2H)ZrCl₃)2

: 37828-54-9
lithium tert-butylamide

: 184899-34-1
(η(5):η(1)-C5H4SiMe2N(t)Bu)ZrCl2

Guidance literature:: In hexane; soln. of Li amide in hexane quickly added at -60.degreeC under Ar to a susp. of equimolar amt. Zr complex in hexane; warmed slowly to room temp.and stirred for 8 h; filtered, concnd., cooled to -40°C; crystalline ppt. collected; recrystn. from toluene at -40°C;
DOI:10.1039/b010221k

Reference yield: 15.0%

: 159771-54-7
Zr(η(5)-C5H4SiMe2Cl)Cl3

: 37828-54-9
lithium tert-butylamide

: 184899-34-1
(η(5):η(1)-C5H4SiMe2N(t)Bu)ZrCl2

: 184899-36-3
Zr(η(5)-C5H4SiMe2NHtBu)Cl3(NEt3)

Guidance literature:: With NEt₃; In toluene; Ar-atmosphere; stirring (room temp., 12 h); filtering, evapn. (reduced pressure), recrystn. (toluene, -40°C);
DOI:10.1021/om960606p