tert-butyldiphenylsilyl 3,4,6-tri-O-benzyl-2-deoxy-2-(4-methoxybenzylideneamino)-β-D-glucopyranose

Base Information

Chemical Name:tert-butyldiphenylsilyl 3,4,6-tri-O-benzyl-2-deoxy-2-(4-methoxybenzylideneamino)-β-D-glucopyranose
CAS No.:1203584-55-7
Molecular Formula:C₅₁H₅₅NO₆Si
Molecular Weight:806.086
Hs Code.:

Synonyms:tert-butyldiphenylsilyl 3,4,6-tri-O-benzyl-2-deoxy-2-(4-methoxybenzylideneamino)-β-D-glucopyranose

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Chemical Property of tert-butyldiphenylsilyl 3,4,6-tri-O-benzyl-2-deoxy-2-(4-methoxybenzylideneamino)-β-D-glucopyranose

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Technology Process of tert-butyldiphenylsilyl 3,4,6-tri-O-benzyl-2-deoxy-2-(4-methoxybenzylideneamino)-β-D-glucopyranose

There total 4 articles about tert-butyldiphenylsilyl 3,4,6-tri-O-benzyl-2-deoxy-2-(4-methoxybenzylideneamino)-β-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₃₀H₃₇NO₆Si

: 100-39-0
benzyl bromide

: 1203584-55-7
tert-butyldiphenylsilyl 3,4,6-tri-O-benzyl-2-deoxy-2-(4-methoxybenzylideneamino)-β-D-glucopyranose

Guidance literature:: With tetra-(n-butyl)ammonium iodide; sodium hydride; In tetrahydrofuran; mineral oil; at 0 ℃; Inert atmosphere; Reflux;
DOI:10.1080/07328300903105108

Reference yield:

: 114297-26-6
1,3,4,6-tetra-O-acetyl-2-deoxy-2-{[(4-methoxyphenyl)methylidene]amino}-D-glucopyranose

: 1203584-55-7
tert-butyldiphenylsilyl 3,4,6-tri-O-benzyl-2-deoxy-2-(4-methoxybenzylideneamino)-β-D-glucopyranose

Guidance literature:: Multi-step reaction with 4 steps

1: ammonia / tetrahydrofuran; methanol / 1.5 h / 0 °C

2: 1H-imidazole / dichloromethane / 2 h / 20 °C / Inert atmosphere

3: methanol; sodium / dichloromethane / 3 h / 20 °C / Inert atmosphere

4: tetra-(n-butyl)ammonium iodide; sodium hydride / tetrahydrofuran; mineral oil / 0 °C / Inert atmosphere; Reflux

With 1H-imidazole; methanol; ammonia; sodium; tetra-(n-butyl)ammonium iodide; sodium hydride; In tetrahydrofuran; methanol; dichloromethane; mineral oil;
DOI:10.1080/07328300903105108

Reference yield:

: 1203584-53-5
tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-methoxybenzylideneamino)-β-D-glucopyranose

: 1203584-55-7
tert-butyldiphenylsilyl 3,4,6-tri-O-benzyl-2-deoxy-2-(4-methoxybenzylideneamino)-β-D-glucopyranose

Guidance literature:: Multi-step reaction with 2 steps

1: methanol; sodium / dichloromethane / 3 h / 20 °C / Inert atmosphere

2: tetra-(n-butyl)ammonium iodide; sodium hydride / tetrahydrofuran; mineral oil / 0 °C / Inert atmosphere; Reflux

With methanol; sodium; tetra-(n-butyl)ammonium iodide; sodium hydride; In tetrahydrofuran; dichloromethane; mineral oil;
DOI:10.1080/07328300903105108