trimethyl(4-(naphthalen-2-yl)phenyl)silane

Base Information

• Chemical Name: trimethyl(4-(naphthalen-2-yl)phenyl)silane
• CAS No.: 1048964-09-5
• Molecular Formula: C₁₉H₂₀Si
• Molecular Weight: 276.453
• Mol file: 1048964-09-5.mol

Synonyms:trimethyl(4-(naphthalen-2-yl)phenyl)silane

Chemical Property of trimethyl(4-(naphthalen-2-yl)phenyl)silane

Chemical Property:

Purity/Quality:

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Technology Process of trimethyl(4-(naphthalen-2-yl)phenyl)silane

There total 5 articles about trimethyl(4-(naphthalen-2-yl)phenyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

2-iodonaphthalene (612-55-5) + C18H26Si2Zn → trimethyl(4-(naphthalen-2-yl)phenyl)silane (1048964-09-5)

Guidance literature:

In tetrahydrofuran; at 110 ℃; for 24h; Inert atmosphere;

DOI:10.1002/ejoc.201301404

Reference yield: 88.0%

2-N,N-Dimethylaminonaphthalene (2436-85-3) + (4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)phenyl)trimethylsilane (574755-28-5) → trimethyl(4-(naphthalen-2-yl)phenyl)silane (1048964-09-5)

Guidance literature:

With 1,3-bis(2,4,6-trimethylphenyl)4,5-dimethyl-1,3-dihydro-2H-imidazol-2-ylidene; magnesium; nickel dibromide; In tetrahydrofuran; at 135 ℃; for 36h; Inert atmosphere; Sealed tube; Schlenk technique;

DOI:10.1021/jacs.8b08779

Reference yield: 71.0%

2-naphthalene carboxylic anhydride (20176-11-8) + (4-(trimethylsilyl)phenyl)boronic acid (17865-11-1) → trimethyl(4-(naphthalen-2-yl)phenyl)silane (1048964-09-5)

Guidance literature:

With bis(tricyclohexylphosphine)nickel(II) dichloride; caesium carbonate; tricyclohexylphosphine; In toluene; at 150 ℃; for 24h; Inert atmosphere; Sealed tube;

DOI:10.1021/acs.joc.0c02266

upstream raw materials:

1-bromo-4-(trimethylsilyl)benzene

2-iodonaphthalene

2-N,N-Dimethylaminonaphthalene

(4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)phenyl)trimethylsilane