(C₂H₄(P(C₆H₅)2)2)2IrS₂O⁽¹⁺⁾*Cl^(1-)=(C₂H₄(P(C₆H₅)2)2)2IrS₂OCl

Base Information

• Chemical Name: (C₂H₄(P(C₆H₅)2)2)2IrS₂O⁽¹⁺⁾*Cl^(1-)=(C₂H₄(P(C₆H₅)2)2)2IrS₂OCl
• CAS No.: 56391-52-7
• Molecular Formula: C₅₂H₄₈IrOP₄S₂*Cl
• Molecular Weight: 1104.65
• Mol file: 56391-52-7.mol

Synonyms:(C₂H₄(P(C₆H₅)2)2)2IrS₂O⁽¹⁺⁾*Cl^(1-)=(C₂H₄(P(C₆H₅)2)2)2IrS₂OCl

Chemical Property of (C₂H₄(P(C₆H₅)2)2)2IrS₂O⁽¹⁺⁾*Cl^(1-)=(C₂H₄(P(C₆H₅)2)2)2IrS₂OCl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₂H₄(P(C₆H₅)2)2)2IrS₂O⁽¹⁺⁾*Cl^(1-)=(C₂H₄(P(C₆H₅)2)2)2IrS₂OCl

There total 2 articles about (C₂H₄(P(C₆H₅)2)2)2IrS₂O⁽¹⁺⁾*Cl^(1-)=(C₂H₄(P(C₆H₅)2)2)2IrS₂OCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

4,5-diphenyl-3,6-dihydro-1,2-dithiine 1-oxide (34826-14-7) + bis(1,2-bis(diphenylphosphino)ethane)iridium(I) chloride (15390-38-2,15131-25-6) → 2,3-diphenyl-1,3-butadiene (2548-47-2) + (C2H4(P(C6H5)2)2)2IrS2O(1+)*Cl(1-)=(C2H4(P(C6H5)2)2)2IrS2OCl (56391-52-7)

Guidance literature:

In not given; identification by spectral comparison to an authentic sample;

DOI:10.1021/om00094a037

Reference yield:

{Ir(S2)(((C6H5)2PCH2)2)2}(1+)*Cl(1-)={Ir(S2)(((C6H5)2PCH2)2)2}Cl (31603-13-1) + 3-chloro-benzenecarboperoxoic acid (937-14-4) → (C2H4(P(C6H5)2)2)2IrS2O(1+)*Cl(1-)=(C2H4(P(C6H5)2)2)2IrS2OCl (56391-52-7) + {Ir(S2O2)(((C6H5)2PCH2)2)2}(1+)*Cl(1-)={Ir(S2O2)(((C6H5)2PCH2)2)2}Cl

Guidance literature:

In dichloromethane; addn. of soln. of m-CPBA to soln. of Ir complex;;

upstream raw materials:

4,5-diphenyl-3,6-dihydro-1,2-dithiine 1-oxide

bis(1,2-bis(diphenylphosphino)ethane)iridium(I) chloride

{Ir(S₂)(((C₆H₅)2PCH₂)2)2}⁽¹⁺⁾*Cl^(1-)={Ir(S₂)(((C₆H₅)2PCH₂)2)2}Cl

3-chloro-benzenecarboperoxoic acid