[3-methoxymethoxy-7-(4-methoxyphenyl)-2-methylene-6-octyloxy-7-phenylheptyl]trimethylsilane

Base Information

Chemical Name:[3-methoxymethoxy-7-(4-methoxyphenyl)-2-methylene-6-octyloxy-7-phenylheptyl]trimethylsilane
CAS No.:503025-58-9
Molecular Formula:C₃₄H₅₄O₄Si
Molecular Weight:554.886
Hs Code.:

Synonyms:[3-methoxymethoxy-7-(4-methoxyphenyl)-2-methylene-6-octyloxy-7-phenylheptyl]trimethylsilane

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Chemical Property of [3-methoxymethoxy-7-(4-methoxyphenyl)-2-methylene-6-octyloxy-7-phenylheptyl]trimethylsilane

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Technology Process of [3-methoxymethoxy-7-(4-methoxyphenyl)-2-methylene-6-octyloxy-7-phenylheptyl]trimethylsilane

There total 11 articles about [3-methoxymethoxy-7-(4-methoxyphenyl)-2-methylene-6-octyloxy-7-phenylheptyl]trimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 503025-52-3
tert-butyldimethyl-[3-(3-phenyloxiranyl)propoxy]silane

: 503025-58-9
[3-methoxymethoxy-7-(4-methoxyphenyl)-2-methylene-6-octyloxy-7-phenylheptyl]trimethylsilane

Guidance literature:: Multi-step reaction with 6 steps

1.1: 71 percent / CuI / tetrahydrofuran / 6 h / 20 °C

2.1: 40 percent / sodium hydride / dimethylformamide / 5 h / 20 °C

3.1: 89 percent / acetic acid / tetrahydrofuran; H₂O

4.1: Dess-Martin periodinane; NaHCO₃ / CH₂Cl₂ / 1 h / 20 °C

5.1: tert-butyllithium / tetrahydrofuran; pentane / 1.25 h / -78 - -20 °C

5.2: MgBr₂ / diethyl ether; pentane; tetrahydrofuran / 0.25 h / -78 °C

6.1: 55 mg / DMAP / various solvent(s) / 5 h / 35 °C

With dmap; tert.-butyl lithium; sodium hydride; sodium hydrogencarbonate; Dess-Martin periodane; acetic acid; copper(l) iodide; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; pentane;
DOI:10.1021/ja029139v

Reference yield:

: 591-50-4
iodobenzene

: 503025-58-9
[3-methoxymethoxy-7-(4-methoxyphenyl)-2-methylene-6-octyloxy-7-phenylheptyl]trimethylsilane

Guidance literature:: Multi-step reaction with 10 steps

1.1: diisopropylamine / Pd(PPh₃)4 / tetrahydrofuran / 0.33 h / 20 °C

1.2: 99 percent / CuI / tetrahydrofuran / 12 h

2.1: 99 percent / LAH / tetrahydrofuran / 20 h / Heating

3.1: 95 percent / imidazole / dimethylformamide / 0 - 20 °C

4.1: 72 percent / m-CPBA; NaOAc / CH₂Cl₂ / 6 h / 20 °C

5.1: 71 percent / CuI / tetrahydrofuran / 6 h / 20 °C

6.1: 40 percent / sodium hydride / dimethylformamide / 5 h / 20 °C

7.1: 89 percent / acetic acid / tetrahydrofuran; H₂O

8.1: Dess-Martin periodinane; NaHCO₃ / CH₂Cl₂ / 1 h / 20 °C

9.1: tert-butyllithium / tetrahydrofuran; pentane / 1.25 h / -78 - -20 °C

9.2: MgBr₂ / diethyl ether; pentane; tetrahydrofuran / 0.25 h / -78 °C

10.1: 55 mg / DMAP / various solvent(s) / 5 h / 35 °C

With 1H-imidazole; dmap; lithium aluminium tetrahydride; tert.-butyl lithium; sodium acetate; sodium hydride; sodium hydrogencarbonate; Dess-Martin periodane; acetic acid; diisopropylamine; 3-chloro-benzenecarboperoxoic acid; copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; pentane;
DOI:10.1021/ja029139v

Reference yield:

: 13159-16-5
(E)-5-phenyl-4-penten-1-ol

: 503025-58-9
[3-methoxymethoxy-7-(4-methoxyphenyl)-2-methylene-6-octyloxy-7-phenylheptyl]trimethylsilane

Guidance literature:: Multi-step reaction with 8 steps

1.1: 95 percent / imidazole / dimethylformamide / 0 - 20 °C

2.1: 72 percent / m-CPBA; NaOAc / CH₂Cl₂ / 6 h / 20 °C

3.1: 71 percent / CuI / tetrahydrofuran / 6 h / 20 °C

4.1: 40 percent / sodium hydride / dimethylformamide / 5 h / 20 °C

5.1: 89 percent / acetic acid / tetrahydrofuran; H₂O

6.1: Dess-Martin periodinane; NaHCO₃ / CH₂Cl₂ / 1 h / 20 °C

7.1: tert-butyllithium / tetrahydrofuran; pentane / 1.25 h / -78 - -20 °C

7.2: MgBr₂ / diethyl ether; pentane; tetrahydrofuran / 0.25 h / -78 °C

8.1: 55 mg / DMAP / various solvent(s) / 5 h / 35 °C

With 1H-imidazole; dmap; tert.-butyl lithium; sodium acetate; sodium hydride; sodium hydrogencarbonate; Dess-Martin periodane; acetic acid; 3-chloro-benzenecarboperoxoic acid; copper(l) iodide; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; pentane;
DOI:10.1021/ja029139v