4,4-{di(6-aminohexanoic acid)-5-amino-N,N'-bis[6-(3,3-dimethylbutyricamino)pyridin-2-yl]isophthalamide-amide}-2,2'-bipyridine

Base Information

• Chemical Name: 4,4-{di(6-aminohexanoic acid)-5-amino-N,N'-bis[6-(3,3-dimethylbutyricamino)pyridin-2-yl]isophthalamide-amide}-2,2'-bipyridine
• CAS No.: 1148156-94-8
• Molecular Formula: C₈₄H₁₀₀N₁₈O₁₂
• Molecular Weight: 1553.83
• Mol file: 1148156-94-8.mol

Synonyms:4,4-{di(6-aminohexanoic acid)-5-amino-N,N'-bis[6-(3,3-dimethylbutyricamino)pyridin-2-yl]isophthalamide-amide}-2,2'-bipyridine

Chemical Property of 4,4-{di(6-aminohexanoic acid)-5-amino-N,N'-bis[6-(3,3-dimethylbutyricamino)pyridin-2-yl]isophthalamide-amide}-2,2'-bipyridine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4,4-{di(6-aminohexanoic acid)-5-amino-N,N'-bis[6-(3,3-dimethylbutyricamino)pyridin-2-yl]isophthalamide-amide}-2,2'-bipyridine

There total 1 articles about 4,4-{di(6-aminohexanoic acid)-5-amino-N,N'-bis[6-(3,3-dimethylbutyricamino)pyridin-2-yl]isophthalamide-amide}-2,2'-bipyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

4,4'-[bis(6-hexanoic acid)amide]-2,2'-bipyridine (1148156-93-7) + 5-amino-N,N'-bis[6-(3,3-dimethylbutyrylamino)pyridin-2-yl]-isophthalamide (717111-10-9) → 4,4-{di(6-aminohexanoic acid)-5-amino-N,N'-bis[6-(3,3-dimethylbutyricamino)pyridin-2-yl]isophthalamide-amide}-2,2'-bipyridine (1148156-94-8)

Guidance literature:

4,4'-[bis(6-hexanoic acid)amide]-2,2'-bipyridine; With dmap; benzotriazol-1-ol; dicyclohexyl-carbodiimide; In N,N-dimethyl-formamide; for 0.5h;

5-amino-N,N'-bis[6-(3,3-dimethylbutyrylamino)pyridin-2-yl]-isophthalamide; In dichloromethane; N,N-dimethyl-formamide; at 20 - 55 ℃; for 120h;

DOI:10.1039/b822043c

Reference yield: 98.4%

ruthenium trichloride hydrate (14898-67-0) + C3H2N3O3(CH2)5COO(CH(CO2CH2C6H5)CH(CO2C6H5)(CO2CH2C6H5)) + 4,4-{di(6-aminohexanoic acid)-5-amino-N,N'-bis[6-(3,3-dimethylbutyricamino)pyridin-2-yl]isophthalamide-amide}-2,2'-bipyridine (1148156-94-8) → Ru(2+)*3C84H100N18O12*6C34H33N3O11*2Cl(1-)=[Ru(C84H100N18O12)3(C34H33N3O11)6]Cl2

Guidance literature:

In ethanol; chloroform; N2; Ru compd., bpy derivative, and ligand (1:3:6 molar ratio) refluxed; evapd., NMR;

DOI:10.1039/b822043c

Reference yield: 55.0%

ruthenium trichloride hydrate (14898-67-0) + 4,4-{di(6-aminohexanoic acid)-5-amino-N,N'-bis[6-(3,3-dimethylbutyricamino)pyridin-2-yl]isophthalamide-amide}-2,2'-bipyridine (1148156-94-8) + hexafluorophosphate anion → Ru(2+)*3C10H6N2(CONH(CH2)5CONHC6H3(CONHC5H3NNHCOCH2C4H9)2)2*2PF6(1-)=[Ru(C84H100N18O12)3][PF6]2 + Ru(4+)*2Cl(1-)*2C10H6N2(CONH(CH2)5CONHC6H3(CONHC5H3NNHCOCH2C4H9)2)2*2PF6(1-)=[RuCl2(C84H100N18O12)2][PF6]2

Guidance literature:

In ethanol; chloroform; N2; Ru compd. and ligand (1:4 molar ratio) under UV control; chromy., recrystd. (acetone/Et2O);

DOI:10.1039/b822043c

upstream raw materials:

4,4'-[bis(6-hexanoic acid)amide]-2,2'-bipyridine

5-amino-N,N'-bis[6-(3,3-dimethylbutyrylamino)pyridin-2-yl]-isophthalamide