[(η5-4-methoxy-1-phenylcyclohexadienyl)Mn(CO)3]

Base Information

Chemical Name:[(η5-4-methoxy-1-phenylcyclohexadienyl)Mn(CO)3]
CAS No.:1276654-35-3
Molecular Formula:C₁₆H₁₃MnO₄
Molecular Weight:324.215
Hs Code.:

Synonyms:[(η5-4-methoxy-1-phenylcyclohexadienyl)Mn(CO)3]

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Chemical Property of [(η5-4-methoxy-1-phenylcyclohexadienyl)Mn(CO)3]

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Technology Process of [(η5-4-methoxy-1-phenylcyclohexadienyl)Mn(CO)3]

There total 2 articles about [(η5-4-methoxy-1-phenylcyclohexadienyl)Mn(CO)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 67-56-1
methanol

: 182004-35-9
tricarbonyl(η(5)-1-chloro-4-methoxy-1-5-cyclohexadienyl)manganese

: 98-80-6
phenylboronic acid

: 182004-44-0
[(η5-1,4-dimethoxycyclohexadienyl)Mn(CO)3]

: 1276654-35-3
[(η5-4-methoxy-1-phenylcyclohexadienyl)Mn(CO)3]

Guidance literature:: With Na₂CO₃; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In methanol; water; (inert atm.); addn. of 1:9 water and methanol to mixt. of phenylboronic acid, manganese compd., palladium compd. and Na2CO3, stirring for 20 minat room temp.; extn. (diethyl ether), washing with water, drying over MgSO4, evapn., chromy. (silica gel, petroleum ether), NMR, IR and MS;
DOI:10.1039/c0dt01270j

Reference yield: 1.0%

: 182004-35-9
tricarbonyl(η(5)-1-chloro-4-methoxy-1-5-cyclohexadienyl)manganese

: 98-80-6
phenylboronic acid

: 1276654-35-3
[(η5-4-methoxy-1-phenylcyclohexadienyl)Mn(CO)3]

Guidance literature:: With Pd₂(C₆H₅CHCHCOCHCHC₆H₅)3; As(C₆H₅)3; Na₂CO₃ or K₂CO₃; In methanol; water; (inert atm.); reaction of manganese compd. and phenylboronic acid in presence of palladium compd., arsine deriv. and carbonate salt in aq. methanol;
DOI:10.1039/c0dt01270j

Reference yield: 90.0%

: 1276654-35-3
[(η5-4-methoxy-1-phenylcyclohexadienyl)Mn(CO)3]

: 341-02-6
trityl tetrafluoroborate

: 455260-26-1,1276654-50-2
[(η6-1-methoxy-4-phenylbenzene)Mn(CO)3]BF4

Guidance literature:: In dichloromethane; (N2); addn. of trityl salt in dry CH2Cl2 to manganese compd. in dry CH2Cl2, stirring at 0°C for 30 min; addn. of dry diethyl ether, filtration, washing with diethyl ether, drying in vac. overnight, NMR, IR and MS;
DOI:10.1039/c0dt01270j