[ReH(OC₂H₅)(CO)(NO)(P(C₆H₅)3)2]

Base Information

• Chemical Name: [ReH(OC₂H₅)(CO)(NO)(P(C₆H₅)3)2]
• CAS No.: 98481-36-8
• Molecular Formula: C₃₉H₃₆NO₃P₂Re
• Molecular Weight: 814.874
• Mol file: 98481-36-8.mol

Synonyms:[ReH(OC₂H₅)(CO)(NO)(P(C₆H₅)3)2]

Chemical Property of [ReH(OC₂H₅)(CO)(NO)(P(C₆H₅)3)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [ReH(OC₂H₅)(CO)(NO)(P(C₆H₅)3)2]

There total 2 articles about [ReH(OC₂H₅)(CO)(NO)(P(C₆H₅)3)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[ReH(C2H5OHOClO3)(CO)(NO)(P(C6H5)3)2] (98481-42-6) → [ReH(OC2H5)(CO)(NO)(P(C6H5)3)2] (98481-36-8)

Guidance literature:

With NaOC₂H₅; In ethanol; dropwise addn. of a NaOC2H5 soln. to a soln. of re-complex in ethanol under N2;; pptn.;;

Reference yield:

[ReH2(nitrosyl)(triphenylphosphine)3] (58694-74-9) + sodium ethanolate (141-52-6) → [ReH(OC2H5)(CO)(NO)(P(C6H5)3)2] (98481-36-8)

Guidance literature:

With CO; HClO₄; In ethanol; dichloromethane; CO was rapidly bubbled through a suspension of the dihydride in CH2Cl2-C2H5OH (1:1) for 20 min; addn. of 70% perchloric acid; dropwise addn. of0.5 M NaOC2H5 soln.; passing CO through soln. for 5 min; N2 atm.;; removal of CH2Cl2 under vac.; pptn.; elem. anal.;;

Reference yield: 100.0%

[ReH(OC2H5)(CO)(NO)(P(C6H5)3)2] (98481-36-8) → [ReH(C2H5OHOClO3)(CO)(NO)(P(C6H5)3)2] (98481-42-6)

Guidance literature:

With HClO₄; In diethyl ether; dichloromethane; addn. of 70% aq. HClO4 to a suspension of Re-complex in CH2Cl2 under N2; addn. of diethyl ether and stirring of the soln.;; pptn.; elem. anal.;;

upstream raw materials:

[ReH₂(nitrosyl)(triphenylphosphine)3]

sodium ethanolate

[ReH(C₂H₅OHOClO₃)(CO)(NO)(P(C₆H₅)3)2]

Downstream raw materials:

[ReH(C₂H₅OHOClO₃)(CO)(NO)(P(C₆H₅)3)2]