trans-bis(tri-tert-butylphosphine)chlorohydridoplatinum(II)

Base Information

• Chemical Name: trans-bis(tri-tert-butylphosphine)chlorohydridoplatinum(II)
• CAS No.: 67901-08-0
• Molecular Formula: C₂₄H₅₅ClP₂Pt
• Molecular Weight: 636.181
• Mol file: 67901-08-0.mol

Synonyms:trans-bis(tri-tert-butylphosphine)chlorohydridoplatinum(II)

Chemical Property of trans-bis(tri-tert-butylphosphine)chlorohydridoplatinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of trans-bis(tri-tert-butylphosphine)chlorohydridoplatinum(II)

There total 1 articles about trans-bis(tri-tert-butylphosphine)chlorohydridoplatinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium tetrahydroborate (16940-66-2) + dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) + tri-tert-butyl phosphine (13716-12-6) → trans-bis(tri-tert-butylphosphine)chlorohydridoplatinum(II) (67901-08-0) + sodium chloride (7647-14-5) + diborane (19287-45-7)

Guidance literature:

In ethanol; byproducts: COD; 1 equiv. of NaBH4, 2 equiv. of phosphine per complex, room temp., few min, gas evolution; evapn., extn. (benzene), recrystn. (benzene/hexane);

DOI:10.1016/S0020-1693(00)93500-X

Reference yield: 95.0%

trans-bis(tri-tert-butylphosphine)chlorohydridoplatinum(II) (67901-08-0) → bis(tri-tert-butylphosphine)platinum(0) (60648-70-6)

Guidance literature:

With sodium methylate; In methanol; soln. of Pt complex in benzene was added to MeOH soln. of MeONe; stirring for 5 h; evapn., extn. with pentane, evapn.;

Reference yield: 90.0%

trans-bis(tri-tert-butylphosphine)chlorohydridoplatinum(II) (67901-08-0) → trans-bis(tri-tert-butylphosphine)platinum(II) dihydride (67870-05-7,1013923-81-3) + bis(tri-tert-butylphosphine)platinum(0) (60648-70-6)

Guidance literature:

With sodium tetrahydroborate; In ethanol; NaBH4 was added to stirred soln. of Pt complex; stirring for 30 min; evapn., extn. with pentane, evapn., recrystn. from hexane; elem. anal.;

upstream raw materials:

sodium tetrahydroborate

dichloro( 1,5-cyclooctadiene)platinum(ll)

tri-tert-butyl phosphine

Downstream raw materials:

bis(tri-tert-butylphosphine)platinum⁽⁰⁾

trans-bis(tri-tert-butylphosphine)platinum(II) dihydride