(1-(4-nitrophenyl)ethyl)(phenyl)sulfane

Base Information

• Chemical Name: (1-(4-nitrophenyl)ethyl)(phenyl)sulfane
• CAS No.: 169059-35-2
• Molecular Formula: C₁₄H₁₃NO₂S
• Molecular Weight: 259.329
• Mol file: 169059-35-2.mol

Synonyms:(1-(4-nitrophenyl)ethyl)(phenyl)sulfane

Chemical Property of (1-(4-nitrophenyl)ethyl)(phenyl)sulfane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1-(4-nitrophenyl)ethyl)(phenyl)sulfane

There total 2 articles about (1-(4-nitrophenyl)ethyl)(phenyl)sulfane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

4-methyl-N'-(1-(4-nitrophenyl)ethylidene)benzenesulfonohydrazide (41780-82-9) + thiophenol (108-98-5) → (1-(4-nitrophenyl)ethyl)(phenyl)sulfane (169059-35-2)

Guidance literature:

With potassium carbonate; In 1,4-dioxane; at 110 ℃; for 24h; Inert atmosphere;

DOI:10.1039/c0ob00639d

Reference yield:

4-nitro-(1-bromoethyl)benzene (19935-81-0) + (phenylthio)trimethylstannane (1007-27-8) → trimethyltin bromide (1066-44-0) + (1-(4-nitrophenyl)ethyl)(phenyl)sulfane (169059-35-2)

Guidance literature:

In chloroform; react. of Sn-compd. with ethane at 90°C for 24 h in a sealed tube; distn.; Kinetics;

DOI:10.1246/bcsj.64.2407

Reference yield:

(1-(4-nitrophenyl)ethyl)(phenyl)sulfane (169059-35-2) → 1-[(S)-1-((S)-Benzenesulfinyl)-ethyl]-4-nitro-benzene + 1-[(S)-1-((R)-Benzenesulfinyl)-ethyl]-4-nitro-benzene

Guidance literature:

With dihydrogen peroxide; In acetic acid; Ambient temperature;

DOI:10.1246/bcsj.62.1891

upstream raw materials:

4-nitro-(1-bromoethyl)benzene

(phenylthio)trimethylstannane

4-methyl-N'-(1-(4-nitrophenyl)ethylidene)benzenesulfonohydrazide

thiophenol

Refernces

• 1、 Ding, Qiuping,Cao, Banpeng,Yuan, Jianjun,Liu, Xianjin,Peng, Yiyuan. "Synthesis of thioethers via metal-free reductive coupling of tosylhydrazones with thiols". supporting information; experimental part. p. 748 - 751. Retrieved 2011/03/22.