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Technology Process of cis-Rh2(N,N'-di-p-anisylformamidinate)2(25,26,27,28-tetra-n-propoxy-5,17-dibromocalix[4]arene-11,23-dicarboxylate)(methanol(ax))

cis-Rh2(N,N'-di-p-anisylformamidinate)2(25,26,27,28-tetra-n-propoxy-5,17-dibromocalix[4]arene-11,23-dicarboxylate)(methanol(ax))

Base Information
  • Chemical Name:cis-Rh2(N,N'-di-p-anisylformamidinate)2(25,26,27,28-tetra-n-propoxy-5,17-dibromocalix[4]arene-11,23-dicarboxylate)(methanol(ax))
  • CAS No.:666827-21-0
  • Molecular Formula:C73H78Br2N4O13Rh2
  • Molecular Weight:1585.06
  • Hs Code.:
cis-Rh<sub>2</sub>(N,N'-di-p-anisylformamidinate)2(25,26,27,28-tetra-n-propoxy-5,17-dibromocalix[4]arene-11,23-dicarboxylate)(methanol(ax))

Synonyms:cis-Rh2(N,N'-di-p-anisylformamidinate)2(25,26,27,28-tetra-n-propoxy-5,17-dibromocalix[4]arene-11,23-dicarboxylate)(methanol(ax))

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Chemical Property of cis-Rh2(N,N'-di-p-anisylformamidinate)2(25,26,27,28-tetra-n-propoxy-5,17-dibromocalix[4]arene-11,23-dicarboxylate)(methanol(ax))
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Technology Process of cis-Rh2(N,N'-di-p-anisylformamidinate)2(25,26,27,28-tetra-n-propoxy-5,17-dibromocalix[4]arene-11,23-dicarboxylate)(methanol(ax))

There total 1 articles about cis-Rh2(N,N'-di-p-anisylformamidinate)2(25,26,27,28-tetra-n-propoxy-5,17-dibromocalix[4]arene-11,23-dicarboxylate)(methanol(ax)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

methanol
67-56-1

methanol

[Rh<sub>2</sub>(cis-N,N'-di-p-anisylformamidinate)2(CH<sub>3</sub>CN(eq))4(CH<sub>3</sub>CN(ax))2](BF<sub>4</sub>)2

[Rh2(cis-N,N'-di-p-anisylformamidinate)2(CH3CN(eq))4(CH3CN(ax))2](BF4)2

(n-Bu<sub>4</sub>N)2(25,26,27,28-tetra-n-propoxy-5,17-dibromocalix[4]arene-11,23-dicarboxylate)

(n-Bu4N)2(25,26,27,28-tetra-n-propoxy-5,17-dibromocalix[4]arene-11,23-dicarboxylate)

cis-Rh<sub>2</sub>(N,N'-di-p-anisylformamidinate)2(25,26,27,28-tetra-n-propoxy-5,17-dibromocalix[4]arene-11,23-dicarboxylate)(methanol(ax))
666827-21-0

cis-Rh2(N,N'-di-p-anisylformamidinate)2(25,26,27,28-tetra-n-propoxy-5,17-dibromocalix[4]arene-11,23-dicarboxylate)(methanol(ax))

Guidance literature:
In acetonitrile; byproducts: n-Bu4NBF4; under N2; ligand salt (1 equiv.) in MeCN added to stirred soln. of Rh complex in MeCN; stirred at ambient temp. (22-25°C) for 24 h; filtered; ppt. washed with MeCN; extd. with CH2Cl2; MeOH layered on the top of soln.; crystd. for several d; elem. anal.;
DOI:10.1021/ja0396899
upstream raw materials:

methanol

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