(1S,2R)-2-{[(tert-butyldiphenylsilyl)oxy]methyl}-1-isopropenylcyclopropane

Base Information

Chemical Name:(1S,2R)-2-{[(tert-butyldiphenylsilyl)oxy]methyl}-1-isopropenylcyclopropane
CAS No.:334705-97-4
Molecular Formula:C₂₃H₃₀OSi
Molecular Weight:350.576
Hs Code.:

Synonyms:(1S,2R)-2-{[(tert-butyldiphenylsilyl)oxy]methyl}-1-isopropenylcyclopropane

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Chemical Property of (1S,2R)-2-{[(tert-butyldiphenylsilyl)oxy]methyl}-1-isopropenylcyclopropane

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Technology Process of (1S,2R)-2-{[(tert-butyldiphenylsilyl)oxy]methyl}-1-isopropenylcyclopropane

There total 3 articles about (1S,2R)-2-{[(tert-butyldiphenylsilyl)oxy]methyl}-1-isopropenylcyclopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 334705-96-3
2-((1S,2R)-2-{[(tert-butyldiphenylsilyl)oxy]methyl}cyclopropyl)propan-2-ol

: 334705-97-4
(1S,2R)-2-{[(tert-butyldiphenylsilyl)oxy]methyl}-1-isopropenylcyclopropane

Guidance literature:: With dmap; methanesulfonyl chloride; triethylamine; In dichloromethane; at 0 ℃; for 5h;
DOI:10.1021/jo0496042

Reference yield:

: 4606-10-4
allyl diazoacetate

: 334705-97-4
(1S,2R)-2-{[(tert-butyldiphenylsilyl)oxy]methyl}-1-isopropenylcyclopropane

Guidance literature:: Multi-step reaction with 3 steps

1.1: 91 percent / Rh₂((5R)-MEPY)4 / CH₂Cl₂ / 30 h / Heating

2.1: diethyl ether; tetrahydrofuran / 0.5 h / 0 °C

2.2: 90 percent / imidazole / diethyl ether; tetrahydrofuran; dimethylformamide / 20 °C

3.1: 85 percent / Et₃N; DMAP; MsCl / CH₂Cl₂ / 5 h / 0 °C

With dmap; methanesulfonyl chloride; triethylamine; Doyle dirhodium catalyst; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/jo0496042

Reference yield:

: 75658-86-5
(1S,5R)-3-oxabicyclo[3.1.0]hexan-2-one

: 334705-97-4
(1S,2R)-2-{[(tert-butyldiphenylsilyl)oxy]methyl}-1-isopropenylcyclopropane

Guidance literature:: Multi-step reaction with 2 steps

1.1: diethyl ether; tetrahydrofuran / 0.5 h / 0 °C

1.2: 90 percent / imidazole / diethyl ether; tetrahydrofuran; dimethylformamide / 20 °C

2.1: 85 percent / Et₃N; DMAP; MsCl / CH₂Cl₂ / 5 h / 0 °C

With dmap; methanesulfonyl chloride; triethylamine; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/jo0496042