[As(C₆H₅)4][(99g)Tc(N)Cl₄]

Base Information

Chemical Name:[As(C₆H₅)4][(99g)Tc(N)Cl₄]
CAS No.:95012-25-2
Molecular Formula:C₂₄H₂₀As*Cl₄NTc
Molecular Weight:638.163
Hs Code.:

[As(C<sub>6</sub>H<sub>5</sub>)4][(99g)Tc(N)Cl<sub>4</sub>]

Synonyms:[As(C₆H₅)4][(99g)Tc(N)Cl₄]

Suppliers and Price of [As(C₆H₅)4][(99g)Tc(N)Cl₄]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [As(C₆H₅)4][(99g)Tc(N)Cl₄]

Chemical Property:

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Technology Process of [As(C₆H₅)4][(99g)Tc(N)Cl₄]

There total 1 articles about [As(C₆H₅)4][(99g)Tc(N)Cl₄] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: As(C₆H₅)4⁽¹⁺⁾*{⁽⁹⁹⁾Tc(NS)Cl₄}^(1-)=As(C₆H₅)4{⁽⁹⁹⁾Tc(NS)Cl₄}

: 95012-25-2
As(C₆H₅)4⁽¹⁺⁾*⁽⁹⁹⁾TcNCl₄^(1-) = (As(C₆H₅)4){⁽⁹⁹⁾TcNCl₄}

Guidance literature:: In not given; byproducts: S8; partial decompn. on storage soln. for 24 h at room; complete decompn. on additional refluxing for 10 min;; not isolated; detected in soln. by EPR spectroscopy;;
DOI:10.1016/S0020-1693(00)89253-1

Reference yield: 90.0%

: 95012-25-2
[As(C₆H₅)4][(99g)Tc(N)Cl₄]

: 603-35-0
triphenylphosphine

: 113945-92-9
dichlorobis(triphenylphosphine)nitridotechnetium(V)

Guidance literature:: With PPh₃; In acetonitrile; AsPh4(TcNCl4) is dissolved in MeCN and then is added a soln. of PPh3 inMeCN; ppt. is collected by filtn., washed with MeCN and dried;

Reference yield: 81.0%

: 95012-25-2
[As(C₆H₅)4][(99g)Tc(N)Cl₄]

: 7550-35-8
lithium bromide

: 129614-02-4
⁽⁹⁹⁾TcNBr₄^(1-)*As(C₆H₅)4⁽¹⁺⁾

Guidance literature:: In acetone; AsPh4(TcNCl4) is dissolved in acetone and then is added a soln. of anhyd. LiBr in acetone, mixt. is heated under reflux for 5 min, acetone is removed and the residue is extd. with dry CH2Cl2; evapn. to dryness, residue is recrystd. from MeCN;