1-ETHYL-2,3-DIMETHYLIMIDAZOLIUM BIS(TRIFLUOROMETHANESULFONYL)IMIDE

Base Information

• Chemical Name: 1-ETHYL-2,3-DIMETHYLIMIDAZOLIUM BIS(TRIFLUOROMETHANESULFONYL)IMIDE
• CAS No.: 174899-90-2
• Molecular Formula: C7H13N2.C2F6NO4S2
• Molecular Weight: 405.339
• Mol file: 174899-90-2.mol

Synonyms:1-ETHYL-2,3-DIMETHYLIMIDAZOLIUM BIS(TRIFLUOROMETHANESULFONYL)IMIDE

Chemical Property of 1-ETHYL-2,3-DIMETHYLIMIDAZOLIUM BIS(TRIFLUOROMETHANESULFONYL)IMIDE

Chemical Property:

• Melting Point: 25 °C
• Refractive Index: 1.4290-1.4330
• PSA: 93.85000
• Density: 1.4913 g/cm3(Temp: 22.9-23.1 °C)
• LogP: 3.86180
• Storage Temp.: Inert atmosphere,Room Temperature

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-Ethyl-2,3-dimethylimidazolium Bis(trifluoromethanesulfonyl)imide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 1-Ethyl-2,3-dimethylimidazolium Bis(trifluoromethanesulfonyl)imide is a useful research chemical.

Technology Process of 1-ETHYL-2,3-DIMETHYLIMIDAZOLIUM BIS(TRIFLUOROMETHANESULFONYL)IMIDE

There total 12 articles about 1-ETHYL-2,3-DIMETHYLIMIDAZOLIUM BIS(TRIFLUOROMETHANESULFONYL)IMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

1-ethyl-2,3-methylimidazolium methyl sulfate (885456-19-9) + bis(trifluoromethane)sulfonimide lithium (90076-65-6) → 1-ethyl-2,3-dimethylimidazolium bis(trifluoromethylsulfonyl)imide (174899-90-2)

Guidance literature:

In water; at 70 ℃; for 4h;

DOI:10.1039/d1ob01031j

Reference yield:

1-ethyl-2,3-dimethyl-3H-imidazole-1-ium chloride (92507-97-6) + bis(trifluoromethane)sulfonimide lithium (90076-65-6) → 1-ethyl-2,3-dimethylimidazolium bis(trifluoromethylsulfonyl)imide (174899-90-2)

Guidance literature:

In water; at 20 ℃; for 72h;

DOI:10.1002/cssc.201100263

Reference yield:

1,2-dimethyl-1H-imidazole (1739-84-0) → 1-ethyl-2,3-dimethylimidazolium bis(trifluoromethylsulfonyl)imide (174899-90-2)

Guidance literature:

Multi-step reaction with 2 steps

1: ethyl acetate / 48 h / 70 °C

2: water / 3 h / 20 °C

In water; ethyl acetate;

DOI:10.1039/c4ra04391j

upstream raw materials:

1-ethyl-2,3-dimethyl-3H-imidazole-1-ium chloride

bis(trifluoromethane)sulfonimide lithium

1,2-dimethyl-1H-imidazole

bis(trifluoromethanesulfonyl)amide

Refernces

• 1、 Alvarez, Marie Stacey,Houzé, Cedric,Groni, Sihem,Sch?llhorn, Bernd,Fave, Claire. "Halogen bonding effect on electrochemical anion oxidation in ionic liquids". supporting information. p. 7587 - 7593. Retrieved 2021/09/22.
• 2、 Yue, Shuwen,Roveda, John D.,Mittenthal, Max S.,Shannon, Matthew S.,Bara, Jason E.. "Experimental Densities and Calculated Fractional Free Volumes of Ionic Liquids with Tri- and Tetra-substituted Imidazolium Cations". . p. 2522 - 2532. Retrieved 2018/07/25.