1-ETHYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE, 99% [EMIIM]

Base Information

• Chemical Name: 1-ETHYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE, 99% [EMIIM]
• CAS No.: 174899-82-2
• Molecular Formula: C8H11F6N3O4S2
• Molecular Weight: 391.315
• Hs Code.: 2935 90 90
• Mol file: 174899-82-2.mol

Synonyms:1-ETHYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE, 99% [EMIIM];1-Ethyl-3-methylimidazolium bis(pentafluoromethanesulfonyl)imide;

Chemical Property of 1-ETHYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE, 99% [EMIIM]

Chemical Property:

• Vapor Pressure: 0.004-0.007Pa at 140.9-150.9℃
• Melting Point: ≥−15 °C(lit.)
• Refractive Index: 1.4220-1.4260
• Boiling Point: 190.5 °C at 760 mmHg
• Flash Point: 69 °C
• PSA: 93.85000
• Density: 1,53 g/cm³
• LogP: 3.55340
• Storage Temp.: Store below +30°C.
• Water Solubility.: Insoluble in water

Purity/Quality:

98% ^*data from raw suppliers

1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,N
• Hazard Codes: T,N
• Statements: 24/25-34-51/53
• Safety Statements: 26-36/37/39-45-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Description: It is a typical ionic liquid usually used as the solvent in the organic synthesis and chemical industry. For example, this chemical can act as the solvent for dissolving CO2 gas.1 This substance may also function as the solvent for dissolving the electroactive oxygen, thus allowing for the study of electrochemical reduction of oxygen by cyclic voltammetry at a gold microdisk electrode.2 Moreover, determination of ammonia based on electro-oxidation of hydroquinone has been carried out by using this compound as the solvent.3 Besides, nanoparticles of ZnO with the wurtzite structure have been synthesized via a microwave through the decomposition of zinc acetate dihydrate in 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide as a solvent.4
• Uses: 1-Ethyl-3-methylimidazolium bis(Trifluoromethylsulfonyl)imide is an ionic liquid; used in method for regulating thermal response temperature of ionic liquid gel and thermal response ionic liquid gel.

Technology Process of 1-ETHYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE, 99% [EMIIM]

There total 16 articles about 1-ETHYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE, 99% [EMIIM] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.9%

triethyloxonium bis(trifluoromethylsulfonyl)imide (945614-34-6) + 1-ethyl-3-methyl-1H-imidazol-3-ium chloride (65039-09-0) → diethyl ether (60-29-7,927820-24-4) + chloroethane (75-00-3) + 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (174899-82-2)

Guidance literature:

at 80 ℃; for 3h;

Reference yield: 95.0%

1-ethyl-3-methylimidazolium bromide → 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (174899-82-2)

Guidance literature:

With bis(trifluoromethane)sulfonimide lithium; In acetone; for 24h;

Reference yield: 92.0%

3-ethyl-1-methyl-1H-imidazol-3-ium bromide (65039-08-9) + bis(trifluoromethane)sulfonimide lithium (90076-65-6) → 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (174899-82-2)

Guidance literature:

In water; for 4h;

DOI:10.1021/acs.inorgchem.7b03191

upstream raw materials:

N-Ethylimidazole

N-methyl bis[(trifluoromethyl)sulfonyl]imide

3-ethyl-1-methyl-1H-imidazol-3-ium bromide

bis(trifluoromethane)sulfonimide lithium

Downstream raw materials:

1-methyl-1H-imidazole

N-Ethylimidazole

N-methyl bis[(trifluoromethyl)sulfonyl]imide

2-Ethylimidazole

Refernces

• 1、 Susan, Md. Abu Bin Hasan,Kaneko, Taketo,Noda, Akihiro,Watanabe, Masayoshi. "Ion gels prepared by in situ radical polymerization of vinyl monomers in an ionic liquid and their characterization as polymer electrolytes". . p. 4976 - 4983. Retrieved 2005.
• 2、 Makino, Takashi,Kanakubo, Mitsuhiro. "NH3absorption in Br?nsted acidic imidazolium- And ammonium-based ionic liquids". . p. 20665 - 20675. Retrieved 2020.
• 3、 Ignat'ev,Willner,Sartori. "Electrochemical fluorination (Simons process) - A powerful tool for the preparation of new conducting salts, ionic liquids and strong Br?nsted acids". . p. 1183 - 1191. Retrieved 2009.
• 4、 Miran Beigi, Ali Akbar,Abdouss, Majid,Yousefi, Maryam,Pourmortazavi, Seied Mahdi,Vahid, Amir. "Investigation on physical and electrochemical properties of three imidazolium based ionic liquids (1-hexyl-3-methylimidazolium tetrafluoroborate, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide and 1-butyl-3-methylimidazolium methylsulfate)". . p. 361 - 368. Retrieved 2013.
• 5、 Wang, Zenghui,Zhao, Pingping,Wu, Jimin,Gao, Jun,Zhang, Lianzheng,Xu, Dongmei. "ZIF-8-porous ionic liquids for the extraction of 2,2,3,3-tetrafluoro-1-propanol and water mixture". . p. 8557 - 8562. Retrieved 2021.
• 6、 Le, My Loan Phung,Tran, Ngoc Anh,Ngo, Hoang Phuong Khanh,Nguyen, Truong Giang,Tran, Van Man. "Liquid Electrolytes Based on Ionic Liquids for Lithium-Ion Batteries". . p. 2332 - 2343. Retrieved 2015.
• 7、 Hoarfrost, Megan L.,He, Yanpu,Lodge, Timothy P.. "Lower critical solution temperature phase behavior of poly(n -butyl methacrylate) in ionic liquid mixtures". . p. 9464 - 9472. Retrieved 2013.
• 8、 Yao, Hongwei,Zhang, Shuheng,Wang, Jieli,Zhou, Qing,Dong, Haifeng,Zhang, Xiangping. "Densities and viscosities of the binary mixtures of 1-ethyl-3- methylimidazolium bis(trifluoromethylsulfonyl)imide with N -methyl-2-pyrrolidone or ethanol at T = (293.15 to 323.15) K". . p. 875 - 881. Retrieved 2012.
• 9、 Grommet, Angela B.,Bolliger, Jeanne L.,Browne, Colm,Nitschke, Jonathan R.. "A Triphasic Sorting System: Coordination Cages in Ionic Liquids". . p. 15100 - 15104. Retrieved 2015.
• 10、 Tsuda, Tetsuya,Sakamoto, Taiki,Nishimura, Yoshitomo,Seino, Satoshi,Imanishi, Akihito,Kuwabata, Susumu. "Various metal nanoparticles produced by accelerated electron beam irradiation of room-temperature ionic liquid". . p. 1925 - 1927. Retrieved 2012.