1-Ethyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imide

Base Information

• Chemical Name: 1-Ethyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imide
• CAS No.: 174899-82-2
• Molecular Formula: C8H11F6N3O4S2
• Molecular Weight: 391.315
• Hs Code.: 2935 90 90
• European Community (EC) Number: 605-741-9,700-235-5
• ChEMBL ID: CHEMBL3185063
• DSSTox Substance ID: DTXSID4047967
• Mol file: 174899-82-2.mol

Synonyms:1-E-3-MIB-TFI;1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

Chemical Property of 1-Ethyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imide

Chemical Property:

• Vapor Pressure: 0.004-0.007Pa at 140.9-150.9℃
• Melting Point: ≥−15 °C(lit.)
• Refractive Index: 1.4220-1.4260
• Boiling Point: 190.5 °C at 760 mmHg
• Flash Point: 69 °C
• PSA: 93.85000
• Density: 1,53 g/cm³
• LogP: 3.55340
• Storage Temp.: Store below +30°C.
• Water Solubility.: Insoluble in water
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 11
• Rotatable Bond Count: 3
• Exact Mass: 391.00951716
• Heavy Atom Count: 23
• Complexity: 447

Purity/Quality:

98% min ^*data from raw suppliers

1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,N
• Hazard Codes: T,N
• Statements: 24/25-34-51/53
• Safety Statements: 26-36/37/39-45-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCN1C=C[N+](=C1)C.C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F
• Description: It is a typical ionic liquid usually used as the solvent in the organic synthesis and chemical industry. For example, this chemical can act as the solvent for dissolving CO2 gas.1 This substance may also function as the solvent for dissolving the electroactive oxygen, thus allowing for the study of electrochemical reduction of oxygen by cyclic voltammetry at a gold microdisk electrode.2 Moreover, determination of ammonia based on electro-oxidation of hydroquinone has been carried out by using this compound as the solvent.3 Besides, nanoparticles of ZnO with the wurtzite structure have been synthesized via a microwave through the decomposition of zinc acetate dihydrate in 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide as a solvent.4
• Uses: 1-Ethyl-3-methylimidazolium bis(Trifluoromethylsulfonyl)imide is an ionic liquid; used in method for regulating thermal response temperature of ionic liquid gel and thermal response ionic liquid gel.

Technology Process of 1-Ethyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imide

There total 16 articles about 1-Ethyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.9%

triethyloxonium bis(trifluoromethylsulfonyl)imide (945614-34-6) + 1-ethyl-3-methyl-1H-imidazol-3-ium chloride (65039-09-0) → diethyl ether (60-29-7,927820-24-4) + chloroethane (75-00-3) + 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (174899-82-2)

Guidance literature:

at 80 ℃; for 3h;

Reference yield: 95.0%

1-ethyl-3-methylimidazolium bromide → 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (174899-82-2)

Guidance literature:

With bis(trifluoromethane)sulfonimide lithium; In acetone; for 24h;

Reference yield: 92.0%

3-ethyl-1-methyl-1H-imidazol-3-ium bromide (65039-08-9) + bis(trifluoromethane)sulfonimide lithium (90076-65-6) → 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (174899-82-2)

Guidance literature:

In water; for 4h;

DOI:10.1021/acs.inorgchem.7b03191

upstream raw materials:

N-Ethylimidazole

N-methyl bis[(trifluoromethyl)sulfonyl]imide

3-ethyl-1-methyl-1H-imidazol-3-ium bromide

bis(trifluoromethane)sulfonimide lithium

Downstream raw materials:

1-methyl-1H-imidazole

N-Ethylimidazole

N-methyl bis[(trifluoromethyl)sulfonyl]imide

2-Ethylimidazole