[Cu(fla)(idpaH)]ClO₄

Base Information

• Chemical Name: [Cu(fla)(idpaH)]ClO₄
• CAS No.: 277314-01-9
• Molecular Formula: C₂₅H₃₄CuN₃O₃*ClO₄
• Molecular Weight: 587.56
• Mol file: 277314-01-9.mol

Synonyms:[Cu(fla)(idpaH)]ClO₄

Chemical Property of [Cu(fla)(idpaH)]ClO₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Cu(fla)(idpaH)]ClO₄

There total 1 articles about [Cu(fla)(idpaH)]ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

copper(II) perchlorate hexahydrate + 3-hydroxyflavone (577-85-5,66585-05-5) + N,N-bis-(3-dimethylaminopropyl)amine (6711-48-4,86003-72-7) → [Cu(fla)(idpaH)]ClO4 (277314-01-9)

Guidance literature:

With piperidine; In methanol; Cu(ClO4)2*6H2O and 3,3'-iminobis(N,N-dimethylpropylamine) in methanol stirred in N2 atmosphere 1 h; flavonol and piperidine added, mixt. stirred at room temp. 2hs; ppt. filtered, recrystd. from acetonitrile, elem. anal.;

DOI:10.1016/S0020-1693(00)00071-2

Reference yield: 62.0%

copper(II)(flavonolate)[3,3'-iminobis(N,N-dimethylpropylamine)]perchlorate (277314-01-9) + oxygen (80937-33-3) → copper(II)(o-benzoylsalicylato)[3,3'-iminobis(N,N-dimethylpropylamine)]perchlorate (277314-03-1)

Guidance literature:

In N,N-dimethyl-formamide; under Ar; Cu complex treated with dioxygen (0.1 MPa) at 100°C for8 h; cooled to room temp., diethyl ether layered on top of soln.; Kinetics;

DOI:10.1016/S1381-1169(03)00456-4

Reference yield: 62.0%

[Cu(fla)(idpaH)]ClO4 (277314-01-9) + oxygen (80937-33-3) → [Cu(idpaH)(o-bs)]ClO4 (277314-03-1)

Guidance literature:

In N,N-dimethyl-formamide; in O2 atmosphere at 100 °C stirred for 8 hs, cooled to room temp., diethyl ether layered on the soln.; pttn.; Kinetics;

DOI:10.1016/S0020-1693(00)00071-2

upstream raw materials:

3-hydroxyflavone

N,N-bis-(3-dimethylaminopropyl)amine

Downstream raw materials:

[Cu(idpaH)(o-bs)]ClO₄

[Cu(3,3'-iminobis(N,N-dimethylpropylamine))(O-benzoylsalicylate)]ClO₄

copper(II)(o-benzoylsalicylato)[3,3'-iminobis(N,N-dimethylpropylamine)]perchlorate