methyl spiro-2'-carboxylate

Base Information

Chemical Name:methyl spiro-2'-carboxylate
CAS No.:124691-66-3
Molecular Formula:C₁₄H₁₅NO₂
Molecular Weight:229.279
Hs Code.:

methyl spiro<cyclopropane-1,3'-(5-phenyl-3,4-dihydropyrrolenine)>-2'-carboxylate

Synonyms:methyl spiro-2'-carboxylate

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Chemical Property of methyl spiro-2'-carboxylate

Chemical Property:

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Technology Process of methyl spiro-2'-carboxylate

There total 4 articles about methyl spiro-2'-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 124691-65-2
methyl 2-azido-2-<1'-(2-phenyl-2'-oxoethyl)cyclopropyl>acetate

: 124691-66-3
methyl spiro-2'-carboxylate

Guidance literature:: With hydrogen sulfide; triethylamine; In pyridine; water; 0 deg C, 1 h, then RT, 12 h;
DOI:10.1016/S0040-4020(01)80123-X

Reference yield:

: 13735-81-4
1-styrenyloxytrimethylsilane

: 124691-66-3
methyl spiro-2'-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 44 percent / TiCl₄ / CH₂Cl₂ / 1 h / -78 °C

2: NaN₃ / dimethylformamide / 12 h / 80 °C

3: 87 percent / H₂S, NEt₃ / pyridine; H₂O / 0 deg C, 1 h, then RT, 12 h

With sodium azide; hydrogen sulfide; titanium tetrachloride; triethylamine; In pyridine; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(01)80123-X

Reference yield:

: 82979-45-1
methyl 2-chloro-2-cyclopropylideneacetate

: 124691-66-3
methyl spiro-2'-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 44 percent / TiCl₄ / CH₂Cl₂ / 1 h / -78 °C

2: NaN₃ / dimethylformamide / 12 h / 80 °C

3: 87 percent / H₂S, NEt₃ / pyridine; H₂O / 0 deg C, 1 h, then RT, 12 h

With sodium azide; hydrogen sulfide; titanium tetrachloride; triethylamine; In pyridine; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(01)80123-X