Bicyclo[3.1.0]hexane-1-carboxylic acid, 4-hydroxy-, methyl ester, (1alpha,4beta,5alpha)-

Base Information

Chemical Name:Bicyclo[3.1.0]hexane-1-carboxylic acid, 4-hydroxy-, methyl ester, (1alpha,4beta,5alpha)-
CAS No.:172908-33-7
Molecular Formula:C₈H₁₂O₃
Molecular Weight:156.181
Hs Code.:
Mol file:172908-33-7.mol

Synonyms:Bicyclo[3.1.0]hexane-1-carboxylicacid, 4-hydroxy-, methyl ester, (1a,4b,5a)- (9CI)

Suppliers and Price of Bicyclo[3.1.0]hexane-1-carboxylic acid, 4-hydroxy-, methyl ester, (1alpha,4beta,5alpha)-

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Bicyclo[3.1.0]hexane-1-carboxylic acid, 4-hydroxy-, methyl ester, (1alpha,4beta,5alpha)-

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of Bicyclo[3.1.0]hexane-1-carboxylic acid, 4-hydroxy-, methyl ester, (1alpha,4beta,5alpha)-

There total 3 articles about Bicyclo[3.1.0]hexane-1-carboxylic acid, 4-hydroxy-, methyl ester, (1alpha,4beta,5alpha)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 25662-28-6
1-(carboxymethoxy)cyclopentadiene

: 172908-33-7
methyl 4-hydroxybicyclo<3.1.0>hexane-1-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: CrO₃, Ac₂O / acetic acid

2: NaBH₄, CeCl₃ / methanol

3: mercuric chloride, samarium / tetrahydrofuran / 2 h / Ambient temperature

With chromium(VI) oxide; samarium; sodium tetrahydroborate; cerium(III) chloride; acetic anhydride; mercury dichloride; In tetrahydrofuran; methanol; acetic acid;
DOI:10.1016/0040-4020(95)00727-P

Reference yield:

: 108384-35-6
methyl 3-oxocyclopent-1-enecarboxylate

: 172908-33-7
methyl 4-hydroxybicyclo<3.1.0>hexane-1-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: NaBH₄, CeCl₃ / methanol

2: mercuric chloride, samarium / tetrahydrofuran / 2 h / Ambient temperature

With samarium; sodium tetrahydroborate; cerium(III) chloride; mercury dichloride; In tetrahydrofuran; methanol;
DOI:10.1016/0040-4020(95)00727-P