162086-59-1

Basic information

• Product Name: 1-Cyclopentene-1-carboxylicacid,3-hydroxy-,methylester(9CI)
• Synonyms: 1-Cyclopentene-1-carboxylicacid,3-hydroxy-,methylester(9CI);methyl 3-hydroxycyclopent-1-enecarboxylate
• CAS NO: 162086-59-1
• Molecular Formula: C₇H₁₀O₃
• Molecular Weight: 142.15
• Product Categories: CARBOXYLICESTER
• Mol File: 162086-59-1.mol
• Article Data: 9

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-Cyclopentene-1-carboxylicacid,3-hydroxy-,methylester(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Cyclopentene-1-carboxylicacid,3-hydroxy-,methylester(9CI)(162086-59-1)
• EPA Substance Registry System: 1-Cyclopentene-1-carboxylicacid,3-hydroxy-,methylester(9CI)(162086-59-1)

Safety Data

• Hazardous Substances Data: 162086-59-1(Hazardous Substances Data)

Usage

Explanation

Different sources of media describe the Explanation of 162086-59-1 differently. You can refer to the following data:
1. The compound has a total of 8 carbon atoms, 12 hydrogen atoms, and 3 oxygen atoms in its molecular structure.
2. At room temperature, the compound appears as a colorless liquid.
3. The compound is known to have a fruity smell.
4. It is derived from 3-hydroxy-1-cyclopentene-1-carboxylic acid with a methyl group attached to the hydroxyl group.
5. Usage in organic synthesis and chemical research
5. The compound is commonly used as an intermediate or reagent in the synthesis of other organic compounds and in various chemical research applications.
6. Applications in pharmaceuticals, agrochemicals, and fine chemicals
6. The compound is utilized in the production of various pharmaceuticals, agrochemicals, and other fine chemicals, making it a valuable compound in these industries.
7. Use as a fragrance and flavoring agent
7. Due to its fruity odor, the compound can be used as a fragrance or flavoring agent in the food and beverage industry.

Appearance

Colorless liquid

Odor

Fruity

Type

Methyl ester derivative

Upstream product

• 2258-56-2 methyl cyclopent-2-ene-1-carboxylate 
• 25662-28-6 1-(carboxymethoxy)cyclopentadiene 
• 162086-60-4 methyl 2,3-epoxycyclopentane-1-carboxylate 
• 108384-35-6 methyl 3-oxocyclopent-1-enecarboxylate 
• 917-54-4 methyllithium 
• 170423-00-4 methyl trans-2,3-epoxy-1-cyclopentancarboxylate 

Downstream Products

• 172908-33-7 methyl 4-hydroxybicyclo<3.1.0>hexane-1-carboxylate 
• 132076-27-8 (R)-methyl 3-oxocyclopentanecarboxylate 
• 132076-32-5 methyl (1S)-3-oxocyclopentanecarboxylate 
• 32811-75-9 methyl 3-oxocyclopentane-1-carboxylate 
• 108384-35-6 methyl 3-oxocyclopent-1-enecarboxylate 
• 1043645-36-8 methyl 3-tert-butyldiphenylsilyloxy-cyclopent-1-ene-carboxylate 

Relevant articles and documents

Biocatalytic synthesis of chiral cyclic γ-oxoesters by sequential C-H hydroxylation, alcohol oxidation and alkene reduction

A three-step biocatalytic procedure is described for the conversion of methyl and ethyl cyclopentene- and cyclohexenecarboxylates into both the enantiomers of the corresponding chiral 3-oxoesters, which are useful building blocks for the synthesis of active pharmaceutical ingredients. The allylic hydroxylation of the starting cycloalkenecarboxylates is carried out by using R. oryzae resting cells entrapped in alginate beads, in acetate buffer solution at 25 °C. The oxidation of the intermediate allylic alcohols to unsaturated ketones, performed by the laccase/TEMPO system, and the ene-reductase mediated hydrogenation of the alkene bond were carried out in the same reaction vessel in a sequential mode at 30 °C. Being entirely biocatalytic, our multistep procedure provides considerable advantages in terms of selectivity and environmental impact over reported chemical methods.

Achieving Regio- and Enantioselectivity of P450-Catalyzed Oxidative CH Activation of Small Functionalized Molecules by Structure-Guided Directed Evolution

Directed evolution of the monooxygenase P450-BM3 utilizing iterative saturation mutagenesis at and near the binding site enables a high degree of both regio- and enantioselectivity in the oxidative hydroxylation of cyclohexene-1-carboxylic acid methyl est

Studies aimed at the total synthesis of azadirachtin. A modeled connection of C-8 and C-14 in azadirachtin

(figure presented) Studies on the connection between the right and left segments of azadirachtin are described. The Ireland-Claisen rearrangement of Li-enolate of the modeled ester with dichlorodimethylsilane in toluene afforded the desired limonoid frame