2-(trimethylsilyl)-2-cyclohexenyl hydroperoxide

Base Information

• Chemical Name: 2-(trimethylsilyl)-2-cyclohexenyl hydroperoxide
• CAS No.: 143100-83-8
• Molecular Formula: C₉H₁₈O₂Si
• Molecular Weight: 186.326
• Mol file: 143100-83-8.mol

Synonyms:2-(trimethylsilyl)-2-cyclohexenyl hydroperoxide

Chemical Property of 2-(trimethylsilyl)-2-cyclohexenyl hydroperoxide

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 2-(trimethylsilyl)-2-cyclohexenyl hydroperoxide

There total 1 articles about 2-(trimethylsilyl)-2-cyclohexenyl hydroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

cyclohex-1-enyl-trimethyl-silane (17874-17-8) → cyclohexenone (930-68-7) + 2-(trimethylsilyl)cyclohex-2-enone (72162-99-3) + 2-(trimethylsilyl)-2-cyclohexenyl hydroperoxide (143100-83-8)

Guidance literature:

With 2,6-di-tert-butyl-4-methyl-phenol; oxygen; rose bengal; In methanol; at -10 ℃; for 23h; Irradiation;

DOI:10.1016/S0040-4039(00)92663-7

Reference yield:

Tosyl isocyanate (4083-64-1) + 2-(trimethylsilyl)-2-cyclohexenyl hydroperoxide (143100-83-8) → C17H25NO5SSi

Guidance literature:

In dichloromethane; at 0 ℃;

DOI:10.1021/jo00097a006

Reference yield:

2-(trimethylsilyl)-2-cyclohexenyl hydroperoxide (143100-83-8) → 2-Trimethylsilanyl-cyclohex-2-enol (71352-18-6)

Guidance literature:

With NaOH buffer; seleno-subtilisin Carlsberg; 5-thio-2-nitrobenzoic acid; citric acid; In ethanol; water; for 0.216667h; pH=5.5;

DOI:10.1021/jo981665a

upstream raw materials:

cyclohex-1-enyl-trimethyl-silane

Downstream raw materials:

2-Trimethylsilanyl-cyclohex-2-enol