1-Cyclohexenyltrimethylsilane

Base Information

• Chemical Name: 1-Cyclohexenyltrimethylsilane
• CAS No.: 17874-17-8
• Molecular Formula: C9H18Si
• Molecular Weight: 154.327
• Hs Code.: 2931900090
• Mol file: 17874-17-8.mol

Synonyms:(1-Cyclohexen-1-yl)trimethylsilane;1-(Trimethylsilyl)-1-cyclohexene;1-Cyclohexenyltrimethylsilane;1-Trimethylsilyl-1-cyclohexene;1-Trimethylsilylcyclohexan-1-ene

Chemical Property of 1-Cyclohexenyltrimethylsilane

Chemical Property:

• PSA: 0.00000
• LogP: 3.36420

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Cyclohexenyltrimethylsilane

There total 19 articles about 1-Cyclohexenyltrimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

chloro-trimethyl-silane (75-77-4) + 1-chlorocyclohexene (930-66-5) → cyclohex-1-enyl-trimethyl-silane (17874-17-8)

Guidance literature:

With sodium; In diethyl ether; at 20 ℃; for 24h;

DOI:10.1055/s-1994-25433

Reference yield: 83.0%

1-bromocyclohex-1-ene (2044-08-8) + chloro-trimethyl-silane (75-77-4) → cyclohex-1-enyl-trimethyl-silane (17874-17-8)

Guidance literature:

With sodium; In diethyl ether; for 4h; Ambient temperature;

DOI:10.1055/s-1980-29178

Reference yield: 67.0%

chloro-trimethyl-silane (75-77-4) + N'-cyclohexylidene-4-methylbenzene-1-sulfonohydrazide (4545-18-0) → cyclohex-1-enyl-trimethyl-silane (17874-17-8)

Guidance literature:

N'-cyclohexylidene-4-methylbenzene-1-sulfonohydrazide; With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In hexane; pentane; at -50 - 20 ℃; Inert atmosphere;

chloro-trimethyl-silane; In hexane; pentane; at 0 - 20 ℃; for 20h; Inert atmosphere;

DOI:10.1002/ejoc.201900726

upstream raw materials:

chloro-trimethyl-silane

1-chlorocyclohexene

N'-cyclohexylidene-4-methylbenzene-1-sulfonohydrazide

cyclohexanone benzenesulfonylhydrazone

Downstream raw materials:

3-methyl-2,3,4,5,6,7-hexahydro-inden-1-one

2-Trimethylsilanyl-cyclohex-2-enol

((1R,2S)-2-Chloro-1-methoxy-cyclohexyl)-trimethyl-silane

r-1-chloro-t-2-methoxy-1-trimethylsilylcyclohexane