bis(tetraphenylphosphonium) dichlorobis(diethyldithiocarbamato)tetrakis(μ3-sulfido)tetraferrate(2II,2III)

Base Information

• Chemical Name: bis(tetraphenylphosphonium) dichlorobis(diethyldithiocarbamato)tetrakis(μ3-sulfido)tetraferrate(2II,2III)
• CAS No.: 88363-93-3
• Molecular Formula: C₁₀H₂₀Cl₂Fe₄N₂S₈*2C₂₄H₂₀P
• Molecular Weight: 1397.9
• Mol file: 88363-93-3.mol

Synonyms:bis(tetraphenylphosphonium) dichlorobis(diethyldithiocarbamato)tetrakis(μ3-sulfido)tetraferrate(2II,2III)

Chemical Property of bis(tetraphenylphosphonium) dichlorobis(diethyldithiocarbamato)tetrakis(μ3-sulfido)tetraferrate(2II,2III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of bis(tetraphenylphosphonium) dichlorobis(diethyldithiocarbamato)tetrakis(μ3-sulfido)tetraferrate(2II,2III)

There total 3 articles about bis(tetraphenylphosphonium) dichlorobis(diethyldithiocarbamato)tetrakis(μ3-sulfido)tetraferrate(2II,2III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

bis(tetraphenylphosphonium) trichloro(diethyldithiocarbamato)tetrakis(μ3-sulfido)tetraferrate(2II,2III)-dimethylformamide (97012-41-4) + sodium diethyldithiocarbamate trihydrate (20624-25-3) → bis(tetraphenylphosphonium) dichlorobis(diethyldithiocarbamato)tetrakis(μ3-sulfido)tetraferrate(2II,2III) (88363-93-3)

Guidance literature:

In acetonitrile; byproducts: NaCl; Fe4S4 complex dissolved in MeCN, Et2NCS2Na*3H2O added with stirring, stirred for 15 min; filtered, Et2O added, stored overnight, crystals collected;

DOI:10.1021/ja00303a018

Reference yield: 79.0%

bis(tetraphenylphosphonium) tetrachlorotetrakis(μ3-sulfido)tetraferrate(2II,2III) + sodium diethyldithiocarbamate trihydrate (20624-25-3) → bis(tetraphenylphosphonium) dichlorobis(diethyldithiocarbamato)tetrakis(μ3-sulfido)tetraferrate(2II,2III) (88363-93-3)

Guidance literature:

In acetonitrile; byproducts: NaCl; to MeCN soln. of Fe4S4 complex was added solid Et2NCS2Na*3H2O while stirring, stirred for ca 40 min; filtered, Et2O added, left standing for ca 4 h, crystals isolated, dried in vac., recrystd. from MeCN/Et2O; elem. anal.;

DOI:10.1021/ja00303a018

Reference yield: 74.0%

bis(tetraphenylphosphonium) bis(diethyldithiocarbamato)bis(thiophenolato)tetrakis(μ3-sulfido)tetraferrate(2II,2III) (83692-59-5) + benzoyl chloride (98-88-4) → bis(tetraphenylphosphonium) dichlorobis(diethyldithiocarbamato)tetrakis(μ3-sulfido)tetraferrate(2II,2III) (88363-93-3)

Guidance literature:

In acetonitrile; to MeCN soln. of Fe4S4 complex was added PhCOCl dropwise, stirred for ca 10 min; filtered, Et2O added, left standing for ca 3 h, crystals collected, dried in vac.;

DOI:10.1021/ja00303a018

upstream raw materials:

bis(tetraphenylphosphonium) bis(diethyldithiocarbamato)bis(thiophenolato)tetrakis(μ3-sulfido)tetraferrate(2II,2III)

benzoyl chloride

bis(tetraphenylphosphonium) trichloro(diethyldithiocarbamato)tetrakis(μ3-sulfido)tetraferrate(2II,2III)-dimethylformamide

sodium diethyldithiocarbamate trihydrate