bis(tetraphenylphosphonium) bis(diethyldithiocarbamato)bis(thiophenolato)tetrakis(μ3-sulfido)tetraferrate(2II,2III)

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Chemical Name:bis(tetraphenylphosphonium) bis(diethyldithiocarbamato)bis(thiophenolato)tetrakis(μ3-sulfido)tetraferrate(2II,2III)
CAS No.:83692-59-5
Molecular Formula:C₂₂H₃₀Fe₄N₂S₁₀*2C₂₄H₂₀P
Molecular Weight:1545.33
Hs Code.:

Synonyms:bis(tetraphenylphosphonium) bis(diethyldithiocarbamato)bis(thiophenolato)tetrakis(μ3-sulfido)tetraferrate(2II,2III)

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Chemical Property of bis(tetraphenylphosphonium) bis(diethyldithiocarbamato)bis(thiophenolato)tetrakis(μ3-sulfido)tetraferrate(2II,2III)

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Technology Process of bis(tetraphenylphosphonium) bis(diethyldithiocarbamato)bis(thiophenolato)tetrakis(μ3-sulfido)tetraferrate(2II,2III)

There total 4 articles about bis(tetraphenylphosphonium) bis(diethyldithiocarbamato)bis(thiophenolato)tetrakis(μ3-sulfido)tetraferrate(2II,2III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 80939-30-6
bis(tetraphenylphosphonium) bis(thiophenolato)dichlorotetrakis(μ3-sulfido)tetraferrate(2II,2III)

: 20624-25-3
sodium diethyldithiocarbamate trihydrate

: 83692-59-5
bis(tetraphenylphosphonium) bis(diethyldithiocarbamato)bis(thiophenolato)tetrakis(μ3-sulfido)tetraferrate(2II,2III)

Guidance literature:: In acetonitrile; to soln. of Fe4S4 complex in MeCN was added solid Et2NCS2Na*3H2O while stirring, stirred for 20 min; filtered, anhyd. Et2O added, left standing for ca 3 h, crystals isolated, dried in vac., recrystd. from MeCN/Et2O (yield 70%); elem. anal.;
DOI:10.1021/ja00303a018

Reference yield: 90.0%

: 80939-30-6
bis(tetraphenylphosphonium) bis(thiophenolato)dichlorotetrakis(μ3-sulfido)tetraferrate(2II,2III)

: 148-18-5
sodium N,N-diethyldithiocarbamate

: 83692-59-5
bis(tetraphenylphosphonium) bis(diethyldithiocarbamato)bis(thiophenolato)tetrakis(μ3-sulfido)tetraferrate(2II,2III)

Guidance literature:: In acetonitrile; Fe-complex reacted with ligand salt (molar ratio 1:2) in MeCN at ambient temp.; filtered, ether added; elem. anal.;