Ru(CO)2(CH₃C(CH₂P(C₆H₅)2)3)

Base Information

• Chemical Name: Ru(CO)2(CH₃C(CH₂P(C₆H₅)2)3)
• CAS No.: 37843-33-7
• Molecular Formula: C₄₃H₃₉O₂P₃Ru
• Molecular Weight: 781.773
• Mol file: 37843-33-7.mol

Synonyms:Ru(CO)2(CH₃C(CH₂P(C₆H₅)2)3)

Chemical Property of Ru(CO)2(CH₃C(CH₂P(C₆H₅)2)3)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Ru(CO)2(CH₃C(CH₂P(C₆H₅)2)3)

There total 1 articles about Ru(CO)2(CH₃C(CH₂P(C₆H₅)2)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hydridodicarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium(1+) hexafluorophosphate (99341-39-6) → dicarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium(0) (37843-33-7)

Guidance literature:

With diethylamine; In dichloromethane; treatment of (RuH(CO)2(triphos))Cl with Et2NH in CH2Cl2; not isolated; detected by IR;

Reference yield: 96.0%

sodium hexaflorophosphate + dicarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium(0) (37843-33-7) → dicarbonylmethyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium(1+) hexafluorophosphate (99299-50-0)

Guidance literature:

With methyl iodide; In ethanol; dichloromethane; under N2, Ru(CO)2(triphos) in CH2Cl2 treated with MeI, stirred at room temp. for 30 min, hexane added, ppt. treated with NaPF6 in EtOH; ppt. collected, washed with EtOH and Et2O, dried in vac. at 80°C; elem. anal.;

Reference yield: 88.0%

Ru(CO)2(CH3C(CH2P(C6H5)2)3) (37843-33-7) + trifluorormethanesulfonic acid (1493-13-6) → C43H40O2P3Ru(1+)*CF3O3S(1-)

Guidance literature:

In dichloromethane; at 20 ℃; for 1.5h; Cooling;

DOI:10.1039/d0gc02528c

upstream raw materials:

hydridodicarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium⁽¹⁺⁾ hexafluorophosphate

Downstream raw materials:

dichlorocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium

chlorodicarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium⁽¹⁺⁾ chloride

diiodocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium

iododicarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium⁽¹⁺⁾ iodide