potassium 4-((tert-butyldimethylsilyl)oxy)-2-(2-nitrophenyl)butanoate

Base Information

Chemical Name:potassium 4-((tert-butyldimethylsilyl)oxy)-2-(2-nitrophenyl)butanoate
CAS No.:1452823-68-5
Molecular Formula:C₁₆H₂₄NO₅Si*K
Molecular Weight:377.554
Hs Code.:

Synonyms:potassium 4-((tert-butyldimethylsilyl)oxy)-2-(2-nitrophenyl)butanoate

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Chemical Property of potassium 4-((tert-butyldimethylsilyl)oxy)-2-(2-nitrophenyl)butanoate

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Technology Process of potassium 4-((tert-butyldimethylsilyl)oxy)-2-(2-nitrophenyl)butanoate

There total 5 articles about potassium 4-((tert-butyldimethylsilyl)oxy)-2-(2-nitrophenyl)butanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 4-((tert-butyldimethylsilyl)oxy)-2-(2-nitrophenyl)butanoic acid

: 1452823-68-5
potassium 4-((tert-butyldimethylsilyl)oxy)-2-(2-nitrophenyl)butanoate

Guidance literature:: With potassium tert-butylate; In ethanol; water; at 20 ℃; for 1h;
DOI:10.1021/ja509329x

Reference yield: 85.0%

: 1452823-70-9
methyl 4-((tert-butyldimethylsilyl)oxy)-2-(2-nitrophenyl)butanoate

: 1452823-68-5
potassium 4-((tert-butyldimethylsilyl)oxy)-2-(2-nitrophenyl)butanoate

Guidance literature:: methyl 4-((tert-butyldimethylsilyl)oxy)-2-(2-nitrophenyl)butanoate; With potassium hydroxide; In tetrahydrofuran; methanol; water; at 20 ℃; Inert atmosphere;

With hydrogenchloride; In tetrahydrofuran; methanol; water; pH=4 - 5; Inert atmosphere;

With potassium tert-butylate; In ethanol; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1002/anie.201209970

Reference yield:

: 30095-98-8
methyl (2-nitrophenyl)acetate

: 1452823-68-5
potassium 4-((tert-butyldimethylsilyl)oxy)-2-(2-nitrophenyl)butanoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: caesium carbonate / N,N-dimethyl-formamide / 60 °C / Inert atmosphere

2.1: potassium hydroxide / tetrahydrofuran; methanol; water / 20 °C / Inert atmosphere

2.2: pH 4 - 5 / Inert atmosphere

2.3: 1 h / 20 °C / Inert atmosphere

With caesium carbonate; potassium hydroxide; In tetrahydrofuran; methanol; water; N,N-dimethyl-formamide;
DOI:10.1002/anie.201209970