Technology Process of diallyl(diphenyl)germane
There total 1 articles about diallyl(diphenyl)germane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
n-butyllithium; sulfuric acid;
In
tetrahydrofuran; tetrachloromethane;
Ar-atmosphere; stirring Zr-complex with 2 equiv. of BuLi at -78°Cfor 1 h (in THF), addn. of equimolar amt. of Ge-compd. at -78°C, stirring (room temp., 2 h), treatment with 10% HCl at 0°C, addn. of Br2 (in CCl4, -78°C); treatment with 10% H2SO4, extn. into ether, washing (aq. NaHCO3, H2O), drying (MgSO4), solvent removal, chromy. (SiO2, hexane/ether=97:3, then 90:10); elem. anal.;
DOI:10.1016/S0022-328X(98)00700-1
- Guidance literature:
-
With
hydrogenchloride; n-butyllithium;
In
tetrahydrofuran;
Ar-atmosphere; stirring Zr-complex with 2 equiv. of BuLi at -78°Cfor 1 h, addn. of equimolar amt. of Ge-compd. at -78°C, stirring (room temp., 2 h), treatment with 10% HCl at 0°C, addn. of exces s PhPCl2 at room temp., stirring 6 h; solvent removal (vac.), extn. into hexane, solvent removal, chromy. (SiO2, CHCl3/CH2Cl2=1:1);
DOI:10.1016/S0022-328X(98)00700-1
