9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-3,4,5,9,10,11-hexaen-1,7,13-triyn-3-yl}phenyl)-9H-carbazole

Base Information

Chemical Name:9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-3,4,5,9,10,11-hexaen-1,7,13-triyn-3-yl}phenyl)-9H-carbazole
CAS No.:1394959-04-6
Molecular Formula:C₈₀H₇₆N₂Si₂
Molecular Weight:1121.67
Hs Code.:

Synonyms:9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-3,4,5,9,10,11-hexaen-1,7,13-triyn-3-yl}phenyl)-9H-carbazole

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Chemical Property of 9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-3,4,5,9,10,11-hexaen-1,7,13-triyn-3-yl}phenyl)-9H-carbazole

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Technology Process of 9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-3,4,5,9,10,11-hexaen-1,7,13-triyn-3-yl}phenyl)-9H-carbazole

There total 4 articles about 9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-3,4,5,9,10,11-hexaen-1,7,13-triyn-3-yl}phenyl)-9H-carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 1394958-97-4
9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-3,12-dihydroxy-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-9H-carbazole

: 1394959-04-6
9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-3,4,5,9,10,11-hexaen-1,7,13-triyn-3-yl}phenyl)-9H-carbazole

Guidance literature:: 9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-3,12-dihydroxy-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-9H-carbazole; With hydrogenchloride; tin(ll) chloride; In diethyl ether; dichloromethane; at -10 - 20 ℃; Inert atmosphere;

With sodium hydroxide; In diethyl ether; dichloromethane; water; Inert atmosphere;
DOI:10.1039/c2cc34176j

Reference yield:

: 801287-71-8
3,6-dimethoxy-3,6-diphenylocta-1,4,7-triyne-1,8-dial

: 1394959-04-6
9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-3,4,5,9,10,11-hexaen-1,7,13-triyn-3-yl}phenyl)-9H-carbazole

Guidance literature:: Multi-step reaction with 4 steps

1.1: n-butyllithium / tetrahydrofuran / 0.67 h / -78 - 20 °C / Inert atmosphere

1.2: -78 - 20 °C / Inert atmosphere

2.1: manganese(IV) oxide / dichloromethane / 3 h / 20 °C / Inert atmosphere

3.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

3.2: 4 h / -78 - -10 °C / Inert atmosphere

4.1: hydrogenchloride; tin(ll) chloride / diethyl ether; dichloromethane / -10 - 20 °C / Inert atmosphere

4.2: Inert atmosphere

With hydrogenchloride; manganese(IV) oxide; n-butyllithium; tin(ll) chloride; In tetrahydrofuran; diethyl ether; hexane; dichloromethane;
DOI:10.1039/c2cc34176j

Reference yield:

: 1394958-94-1
{12-hydroxy-3,6,9-trimethoxy-6,9-diphenyl-14-[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-1-yl}tris(propan-2-yl)silane

: 1394959-04-6
9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-3,4,5,9,10,11-hexaen-1,7,13-triyn-3-yl}phenyl)-9H-carbazole

Guidance literature:: Multi-step reaction with 3 steps

1.1: manganese(IV) oxide / dichloromethane / 3 h / 20 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

2.2: 4 h / -78 - -10 °C / Inert atmosphere

3.1: hydrogenchloride; tin(ll) chloride / diethyl ether; dichloromethane / -10 - 20 °C / Inert atmosphere

3.2: Inert atmosphere

With hydrogenchloride; manganese(IV) oxide; n-butyllithium; tin(ll) chloride; In tetrahydrofuran; diethyl ether; hexane; dichloromethane;
DOI:10.1039/c2cc34176j