(9-(4-BROMOPHENYL))-9H-CARBAZOLE

Base Information

• Chemical Name: (9-(4-BROMOPHENYL))-9H-CARBAZOLE
• CAS No.: 57102-42-8
• Molecular Formula: C18H12BrN
• Molecular Weight: 322.204
• Hs Code.: 29339900
• Mol file: 57102-42-8.mol

Synonyms:Carbazole,9-(p-bromophenyl)- (6CI);1-(9-N-Carbazolyl)-4-bromobenzene;1-Bromo-4-(carbazol-9-yl)benzene;9-(4-Bromophenyl)-9H-carbazole;N-(4-Bromophenyl)-9H-carbazole;N-(4-Bromophenyl)carbazole;

Chemical Property of (9-(4-BROMOPHENYL))-9H-CARBAZOLE

Chemical Property:

• Vapor Pressure: 2.2E-08mmHg at 25°C
• Melting Point: 147-151℃
• Refractive Index: 1.672
• Boiling Point: 452.672 °C at 760 mmHg
• Flash Point: 227.568 °C
• PSA: 4.93000
• Density: 1.391 g/cm³
• LogP: 5.54620
• Storage Temp.: Sealed in dry,Room Temperature
• Water Solubility.: Slightly soluble in water.

Purity/Quality:

99.0%Min ^*data from raw suppliers

9-(4-Bromophenyl)carbazole >98.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: It plays an important role as intermediate for pharmaceutical, organic synthesis and organic light-emitting diode(OLED).

Technology Process of (9-(4-BROMOPHENYL))-9H-CARBAZOLE

There total 24 articles about (9-(4-BROMOPHENYL))-9H-CARBAZOLE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1,4-bromoiodobenzene (589-87-7) + 9H-carbazole (86-74-8,105184-46-1,97960-57-1) → N-(4-bromophenyl)carbazole (57102-42-8)

Guidance literature:

With copper(l) iodide; 1,10-Phenanthroline; potassium hydroxide; In 1,2-dimethoxyethane; water; at 95 ℃; for 20h; Solvent; Catalytic behavior; Schlenk technique; Inert atmosphere; Sealed tube;

DOI:10.1002/ejoc.201901542

Reference yield: 98.46%

[1,1'-biphenyl]-2,2'-iodonium trifluoromethanesulfonate (189999-35-7) + 4-bromo-aniline (106-40-1) → N-(4-bromophenyl)carbazole (57102-42-8)

Guidance literature:

With copper diacetate; sodium carbonate; In ethylene glycol; isopropyl alcohol; at 90 ℃; for 16h;

DOI:10.1016/j.ejmech.2013.07.029

Reference yield: 96.0%

9H-carbazole (86-74-8,105184-46-1,97960-57-1) + (4-bromophenyl)hydrazine (589-21-9) → N-(4-bromophenyl)carbazole (57102-42-8)

Guidance literature:

With palladium diacetate; cesium fluoride; In acetonitrile; at 60 ℃; for 12h; Schlenk technique;

upstream raw materials:

1,4-bromoiodobenzene

9H-carbazole

1.4-dibromobenzene

copper(I) iodide

Downstream raw materials:

9‐(4‐bromophenyl)‐3,6‐diiodocarbazole

C₁₈H₁₂LiN

3,6-dibromo-9-(4-bromophenyl)-9H-carbazole

4-(carbazol-9-yl)phenylboronic acid

Refernces

• 1、 Lv, Hai-juan,Ma, Rong-fang,Zhang, Xiao-tai,Li, Mei-han,Wang, Yu-tong,Wang, Shu,Xing, Guo-wen. "Surfactant-modulated discriminative sensing of HNO and H2S with a Cu2+-complex-based fluorescent probe". . p. 5495 - 5501. Retrieved 2016.
• 2、 Jeon, Ji Young,Park, Tae Jin,Jeon, Woo Sik,Park, Jung Joo,Jang, Jin,Kwon, Jang Hyuk,Lee, Jae Yeol. "Bipolar host materials for green triplet emitter in organic light-emitting diodes". . p. 1156 - 1157. Retrieved 2007.
• 3、 Park, Yoona,Jung, Joori,Jeon, Hani,Lee, Sunhee,Han, Won-Sik. "Crystal structure of 9,9′-(4,4′-(silinane-1,1-diyl)bis(4,1-phenylene))bis(9H-carbazole) and its photophysical and electrochemical properties". . p. 23 - 27. Retrieved 2018.
• 4、 Biesen, Lukas,May, Lars,Nirmalananthan-Budau, Nithiya,Hoffmann, Katrin,Resch-Genger, Ute,Müller, Thomas J. J.. "Communication of Bichromophore Emission upon Aggregation – Aroyl-S,N-ketene Acetals as Multifunctional Sensor Merocyanines". supporting information. p. 13426 - 13434. Retrieved 2021/08/06.
• 5、 Yin, Zheng,Gu, Mingxing,Ma, Huili,Jiang, Xueyan,Zhi, Jiahuan,Wang, Yafei,Yang, Huifang,Zhu, Weiguo,An, Zhongfu. "Molecular Engineering through Control of Structural Deformation for Highly Efficient Ultralong Organic Phosphorescence". supporting information. p. 2058 - 2063. Retrieved 2020/11/30.