9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-3,12-dihydroxy-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-9H-carbazole

Base Information

• Chemical Name: 9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-3,12-dihydroxy-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-9H-carbazole
• CAS No.: 1394958-97-4
• Molecular Formula: C₈₂H₈₄N₂O₄Si₂
• Molecular Weight: 1217.75
• Mol file: 1394958-97-4.mol

Synonyms:9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-3,12-dihydroxy-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-9H-carbazole

Chemical Property of 9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-3,12-dihydroxy-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-9H-carbazole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-3,12-dihydroxy-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-9H-carbazole

There total 2 articles about 9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-3,12-dihydroxy-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-9H-carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

N-(4-bromophenyl)carbazole (57102-42-8) + {6,9-dimethoxy-3,12-dioxo-6,9-diphenyl-14-[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-1-yl}tris(propan-2-yl)silane (1394958-95-2) → 9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-3,12-dihydroxy-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-9H-carbazole (1394958-97-4)

Guidance literature:

N-(4-bromophenyl)carbazole; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

{6,9-dimethoxy-3,12-dioxo-6,9-diphenyl-14-[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-1-yl}tris(propan-2-yl)silane; In tetrahydrofuran; hexane; at -78 - -10 ℃; for 4h; Inert atmosphere;

DOI:10.1039/c2cc34176j

Reference yield: 82.0%

C18H12LiN (189878-22-6) + {6,9-dimethoxy-3,12-dioxo-6,9-diphenyl-14-[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-1-yl}tris(propan-2-yl)silane (1394958-95-2) → 9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-3,12-dihydroxy-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-9H-carbazole (1394958-97-4)

Guidance literature:

C₁₈H₁₂LiN; {6,9-dimethoxy-3,12-dioxo-6,9-diphenyl-14-[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-1-yl}tris(propan-2-yl)silane; Inert atmosphere; Schlenk technique;

Acidic conditions; Inert atmosphere; Schlenk technique;

DOI:10.1002/chem.201303169

Reference yield: 52.0%

9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-3,12-dihydroxy-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-9H-carbazole (1394958-97-4) → 9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-3,4,5,9,10,11-hexaen-1,7,13-triyn-3-yl}phenyl)-9H-carbazole (1394959-04-6)

Guidance literature:

9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-3,12-dihydroxy-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-9H-carbazole; With hydrogenchloride; tin(ll) chloride; In diethyl ether; dichloromethane; at -10 - 20 ℃; Inert atmosphere;

With sodium hydroxide; In diethyl ether; dichloromethane; water; Inert atmosphere;

DOI:10.1039/c2cc34176j

upstream raw materials:

N-(4-bromophenyl)carbazole

{6,9-dimethoxy-3,12-dioxo-6,9-diphenyl-14-[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-1-yl}tris(propan-2-yl)silane

C₁₈H₁₂LiN

Downstream raw materials:

9-(4-{12-[4-(9H-carbazol-9-yl)phenyl]-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-3,4,5,9,10,11-hexaen-1,7,13-triyn-3-yl}phenyl)-9H-carbazole