(E)-(2S,10R)-2-benzyloxy-1-{(4R,6S)-6-(2-hydroxyethyl)-2,2-dimethyl[1,3]dioxan-4-yl}-11-(4-methoxy-benzyloxy)-3,3-dimethyl-10-triethylsilyloxy-8-[(Z)-2-tri-isopropylsilyloxyethylidene]undec-5-en-4-one

Base Information

Chemical Name:(E)-(2S,10R)-2-benzyloxy-1-{(4R,6S)-6-(2-hydroxyethyl)-2,2-dimethyl[1,3]dioxan-4-yl}-11-(4-methoxy-benzyloxy)-3,3-dimethyl-10-triethylsilyloxy-8-[(Z)-2-tri-isopropylsilyloxyethylidene]undec-5-en-4-one
CAS No.:1314756-91-6
Molecular Formula:C₅₃H₈₈O₉Si₂
Molecular Weight:925.447
Hs Code.:

(E)-(2S,10R)-2-benzyloxy-1-{(4R,6S)-6-(2-hydroxyethyl)-2,2-dimethyl[1,3]dioxan-4-yl}-11-(4-methoxy-benzyloxy)-3,3-dimethyl-10-triethylsilyloxy-8-[(Z)-2-tri-isopropylsilyloxyethylidene]undec-5-en-4-one

Synonyms:(E)-(2S,10R)-2-benzyloxy-1-{(4R,6S)-6-(2-hydroxyethyl)-2,2-dimethyl[1,3]dioxan-4-yl}-11-(4-methoxy-benzyloxy)-3,3-dimethyl-10-triethylsilyloxy-8-[(Z)-2-tri-isopropylsilyloxyethylidene]undec-5-en-4-one

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Chemical Property of (E)-(2S,10R)-2-benzyloxy-1-{(4R,6S)-6-(2-hydroxyethyl)-2,2-dimethyl[1,3]dioxan-4-yl}-11-(4-methoxy-benzyloxy)-3,3-dimethyl-10-triethylsilyloxy-8-[(Z)-2-tri-isopropylsilyloxyethylidene]undec-5-en-4-one

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Technology Process of (E)-(2S,10R)-2-benzyloxy-1-{(4R,6S)-6-(2-hydroxyethyl)-2,2-dimethyl[1,3]dioxan-4-yl}-11-(4-methoxy-benzyloxy)-3,3-dimethyl-10-triethylsilyloxy-8-[(Z)-2-tri-isopropylsilyloxyethylidene]undec-5-en-4-one

There total 9 articles about (E)-(2S,10R)-2-benzyloxy-1-{(4R,6S)-6-(2-hydroxyethyl)-2,2-dimethyl[1,3]dioxan-4-yl}-11-(4-methoxy-benzyloxy)-3,3-dimethyl-10-triethylsilyloxy-8-[(Z)-2-tri-isopropylsilyloxyethylidene]undec-5-en-4-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1314756-90-5
dimethyl (4S)-4-benzyloxy-5-[(4R,6S)-6-(2-hydroxyethyl)-2,2-dimethyl-1,3-dioxan-4-yl]-3,3-dimethyl-2-oxopentylphosphonate

: C₃₁H₅₆O₅Si₂

: 1314756-91-6
(E)-(2S,10R)-2-benzyloxy-1-{(4R,6S)-6-(2-hydroxyethyl)-2,2-dimethyl[1,3]dioxan-4-yl}-11-(4-methoxy-benzyloxy)-3,3-dimethyl-10-triethylsilyloxy-8-[(Z)-2-tri-isopropylsilyloxyethylidene]undec-5-en-4-one

Guidance literature:: dimethyl (4S)-4-benzyloxy-5-[(4R,6S)-6-(2-hydroxyethyl)-2,2-dimethyl-1,3-dioxan-4-yl]-3,3-dimethyl-2-oxopentylphosphonate; With 0.8H₂O*BaH₂O₂; In tetrahydrofuran; at 20 ℃; for 0.5h;

C₃₁H₅₆O₅Si₂; In tetrahydrofuran; water; at 20 ℃; for 16h;
DOI:10.1039/c7ob02129a

Reference yield:

: 807365-26-0
((S)-4-Benzyloxy-5-{(4R,6S)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-3,3-dimethyl-2-oxo-pentyl)-phosphonic acid dimethyl ester

: 1314756-91-6
(E)-(2S,10R)-2-benzyloxy-1-{(4R,6S)-6-(2-hydroxyethyl)-2,2-dimethyl[1,3]dioxan-4-yl}-11-(4-methoxy-benzyloxy)-3,3-dimethyl-10-triethylsilyloxy-8-[(Z)-2-tri-isopropylsilyloxyethylidene]undec-5-en-4-one

Guidance literature:: Multi-step reaction with 2 steps

1: tetrabutyl ammonium fluoride / tetrahydrofuran / 16 h / 20 °C

2: 0.8H₂O*BaH₂O₂ / tetrahydrofuran; water / 16 h / 0 - 20 °C

With 0.8H₂O*BaH₂O₂; tetrabutyl ammonium fluoride; In tetrahydrofuran; water;
DOI:10.1039/c1cc12332g