Acetic acid (3aS,4R,6R,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester

Base Information

Chemical Name:Acetic acid (3aS,4R,6R,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester
CAS No.:874910-84-6
Molecular Formula:C₂₇H₃₆O₅Si
Molecular Weight:468.665
Hs Code.:

Synonyms:Acetic acid (3aS,4R,6R,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester

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Chemical Property of Acetic acid (3aS,4R,6R,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester

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Technology Process of Acetic acid (3aS,4R,6R,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester

There total 5 articles about Acetic acid (3aS,4R,6R,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 869710-95-2
(1S,4S)-4-Hydroxymethyl-cyclopent-2-enol

: 874910-84-6
Acetic acid (3aS,4R,6R,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 70 percent / imidazole / CH₂Cl₂

2: TPP; DIAD / tetrahydrofuran

3: NMO; OsO₄ / acetone; tetrahydrofuran; H₂O

4: pTSA / acetone

With 1H-imidazole; osmium(VIII) oxide; N-methyl-2-indolinone; di-isopropyl azodicarboxylate; thiamine diphosphate; toluene-4-sulfonic acid; In tetrahydrofuran; dichloromethane; water; acetone; 2: Mitsunobu reaction;
DOI:10.1016/j.tetlet.2005.08.163

Reference yield:

: (1S,4S)-4-[(Isopropoxy-dimethyl-silanyl)-methyl]-cyclopent-2-enol

: 874910-84-6
Acetic acid (3aS,4R,6R,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 87 percent / H₂O₂; KF / methanol; tetrahydrofuran; H₂O

2: 70 percent / imidazole / CH₂Cl₂

3: TPP; DIAD / tetrahydrofuran

4: NMO; OsO₄ / acetone; tetrahydrofuran; H₂O

5: pTSA / acetone

With 1H-imidazole; potassium fluoride; osmium(VIII) oxide; N-methyl-2-indolinone; di-isopropyl azodicarboxylate; dihydrogen peroxide; thiamine diphosphate; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; dichloromethane; water; acetone; 1: Tamao oxidation / 3: Mitsunobu reaction;
DOI:10.1016/j.tetlet.2005.08.163

Reference yield:

: 869710-97-4
(1S,4S)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-cyclopent-2-enol

: 874910-84-6
Acetic acid (3aS,4R,6R,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl ester

Guidance literature:: Multi-step reaction with 3 steps

1: TPP; DIAD / tetrahydrofuran

2: NMO; OsO₄ / acetone; tetrahydrofuran; H₂O

3: pTSA / acetone

With osmium(VIII) oxide; N-methyl-2-indolinone; di-isopropyl azodicarboxylate; thiamine diphosphate; toluene-4-sulfonic acid; In tetrahydrofuran; water; acetone; 1: Mitsunobu reaction;
DOI:10.1016/j.tetlet.2005.08.163