N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide-9,10-dicarboxylic acid anhydride

Base Information

• Chemical Name: N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide-9,10-dicarboxylic acid anhydride
• CAS No.: 946850-59-5
• Molecular Formula: C₃₆H₂₅NO₅
• Molecular Weight: 551.598
• Mol file: 946850-59-5.mol

Synonyms:N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide-9,10-dicarboxylic acid anhydride

Chemical Property of N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide-9,10-dicarboxylic acid anhydride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide-9,10-dicarboxylic acid anhydride

There total 3 articles about N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide-9,10-dicarboxylic acid anhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide-9,10-dicarboxylic acid-9,10-bis(decylester) → N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide-9,10-dicarboxylic acid anhydride (946850-59-5)

Guidance literature:

With toluene-4-sulfonic acid; In toluene; at 95 ℃; for 4h; Inert atmosphere;

DOI:10.1021/jacs.0c10457

Reference yield:

2,6-diisopropylbenzenamine (24544-04-5) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide-9,10-dicarboxylic acid anhydride (946850-59-5)

Guidance literature:

With 1H-imidazole; at 140 ℃; for 2h;

DOI:10.1002/chem.201300439

Reference yield:

tetrakis(decyl)perylene-3,4,9,10-tetracarboxylate (288587-52-0) → N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide-9,10-dicarboxylic acid anhydride (946850-59-5)

Guidance literature:

Multi-step reaction with 3 steps

1: toluene-4-sulfonic acid / toluene; dodecane / 6 h / 95 °C

2: dmap; 1H-imidazole / 19 h / 140 °C / Inert atmosphere

3: toluene-4-sulfonic acid / toluene / 4 h / 95 °C / Inert atmosphere

With 1H-imidazole; dmap; toluene-4-sulfonic acid; In dodecane; toluene;

DOI:10.1021/jacs.0c10457

upstream raw materials:

2,6-diisopropylbenzenamine

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

tetrakis(decyl)perylene-3,4,9,10-tetracarboxylate

Downstream raw materials:

Lumogen F Orange 240