(5R)-phenyliodonium 1-[(nonafluorobutyl)sulfonyl]-2-oxo-5-phenylhexylide

Base Information

Chemical Name:(5R)-phenyliodonium 1-[(nonafluorobutyl)sulfonyl]-2-oxo-5-phenylhexylide
CAS No.:446879-35-2
Molecular Formula:C₂₂H₁₈F₉IO₃S
Molecular Weight:660.339
Hs Code.:

Synonyms:(5R)-phenyliodonium 1-[(nonafluorobutyl)sulfonyl]-2-oxo-5-phenylhexylide

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Chemical Property of (5R)-phenyliodonium 1-[(nonafluorobutyl)sulfonyl]-2-oxo-5-phenylhexylide

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Technology Process of (5R)-phenyliodonium 1-[(nonafluorobutyl)sulfonyl]-2-oxo-5-phenylhexylide

There total 5 articles about (5R)-phenyliodonium 1-[(nonafluorobutyl)sulfonyl]-2-oxo-5-phenylhexylide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 3240-34-4
[bis(acetoxy)iodo]benzene

: 446879-34-1
(R)-1-[(nonafluorobutyl)sulfonyl]-5-phenylhexan-2-one

: 446879-35-2
(5R)-phenyliodonium 1-[(nonafluorobutyl)sulfonyl]-2-oxo-5-phenylhexylide

Guidance literature:: With triethylamine; In dichloromethane; at 20 ℃; for 0.166667h;
DOI:10.1002/1522-2675(200202)85:2<483::AID-HLCA483>3.0.CO;2-Q

Reference yield:

: 37778-99-7
(S)-2-phenyl-1-propanol

: 446879-35-2
(5R)-phenyliodonium 1-[(nonafluorobutyl)sulfonyl]-2-oxo-5-phenylhexylide

Guidance literature:: Multi-step reaction with 3 steps

1.1: 85 percent / Ph₃P; 1H-imidazole; I₂ / diethyl ether; acetonitrile / 3 h / 20 °C

2.1: BuLi; diisopropylamine / hexane; tetrahydrofuran / 0.5 h / -25 °C

2.2: 53 percent / HMPA / tetrahydrofuran; hexane / 1 h / 20 °C

3.1: 75 percent / Et₃N / CH₂Cl₂ / 0.17 h / 20 °C

With 1H-imidazole; n-butyllithium; iodine; triethylamine; diisopropylamine; triphenylphosphine; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; acetonitrile;
DOI:10.1002/1522-2675(200202)85:2<483::AID-HLCA483>3.0.CO;2-Q

Reference yield:

: 40630-22-6
1,1,1,2,2,3,3,4,4-nonafluoro-4-(methylsulfonyl)butane

: 446879-35-2
(5R)-phenyliodonium 1-[(nonafluorobutyl)sulfonyl]-2-oxo-5-phenylhexylide

Guidance literature:: Multi-step reaction with 3 steps

1.1: (i-Pr)2NH; BuLi / tetrahydrofuran; hexane / 0.5 h / -78 °C

1.2: 76 percent / tetrahydrofuran; hexane / 1 h / -78 °C

2.1: BuLi; diisopropylamine / hexane; tetrahydrofuran / 0.5 h / -25 °C

2.2: 53 percent / HMPA / tetrahydrofuran; hexane / 1 h / 20 °C

3.1: 75 percent / Et₃N / CH₂Cl₂ / 0.17 h / 20 °C

With n-butyllithium; triethylamine; diisopropylamine; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1002/1522-2675(200202)85:2<483::AID-HLCA483>3.0.CO;2-Q