chlorodicarbonyl(3-methyl-1,4-bis(2,4,6-trimethylphenyl)-1,2,3-triazol-5-ylidene)iridium(I)

Base Information

• Chemical Name: chlorodicarbonyl(3-methyl-1,4-bis(2,4,6-trimethylphenyl)-1,2,3-triazol-5-ylidene)iridium(I)
• CAS No.: 1370328-81-6
• Molecular Formula: C₂₃H₂₅ClIrN₃O₂
• Molecular Weight: 603.143
• Mol file: 1370328-81-6.mol

Synonyms:chlorodicarbonyl(3-methyl-1,4-bis(2,4,6-trimethylphenyl)-1,2,3-triazol-5-ylidene)iridium(I)

Chemical Property of chlorodicarbonyl(3-methyl-1,4-bis(2,4,6-trimethylphenyl)-1,2,3-triazol-5-ylidene)iridium(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chlorodicarbonyl(3-methyl-1,4-bis(2,4,6-trimethylphenyl)-1,2,3-triazol-5-ylidene)iridium(I)

There total 1 articles about chlorodicarbonyl(3-methyl-1,4-bis(2,4,6-trimethylphenyl)-1,2,3-triazol-5-ylidene)iridium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

bis(1,5-cyclooctadiene)diiridium(I) dichloride (12112-67-3) + carbon monoxide (201230-82-2) + 3-methyl-1,4-bis(2,4,6-trimethylphenyl)-1H-1,2,3-triazolium tetrafluoroborate (1263862-40-3) → chlorodicarbonyl(3-methyl-1,4-bis(2,4,6-trimethylphenyl)-1,2,3-triazol-5-ylidene)iridium(I) (1370328-81-6)

Guidance literature:

With (CH₃)3COK; In not given; C2HN3(Me)(Mes)2BF4 treated with tBuOK, (IrCl(cod))2 added, mixt. treatedwith excess of CO; G. Guisado-Barrios et al., Angew. Chem, Int. Ed. 201 0, 49, 4759-4762; elem. anal.;

DOI:10.1002/ejic.201101383

upstream raw materials:

bis(1,5-cyclooctadiene)diiridium(I) dichloride

carbon monoxide

3-methyl-1,4-bis(2,4,6-trimethylphenyl)-1H-1,2,3-triazolium tetrafluoroborate