chlorodicarbonyl(3-methyl-1,4-bis(2,4,6-trimethylphenyl)-1,2,3-triazol-5-ylidene)iridium(I)

Base Information

Chemical Name:chlorodicarbonyl(3-methyl-1,4-bis(2,4,6-trimethylphenyl)-1,2,3-triazol-5-ylidene)iridium(I)
CAS No.:1370328-81-6
Molecular Formula:C₂₃H₂₅ClIrN₃O₂
Molecular Weight:603.143
Hs Code.:

Synonyms:chlorodicarbonyl(3-methyl-1,4-bis(2,4,6-trimethylphenyl)-1,2,3-triazol-5-ylidene)iridium(I)

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Chemical Property of chlorodicarbonyl(3-methyl-1,4-bis(2,4,6-trimethylphenyl)-1,2,3-triazol-5-ylidene)iridium(I)

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Technology Process of chlorodicarbonyl(3-methyl-1,4-bis(2,4,6-trimethylphenyl)-1,2,3-triazol-5-ylidene)iridium(I)

There total 1 articles about chlorodicarbonyl(3-methyl-1,4-bis(2,4,6-trimethylphenyl)-1,2,3-triazol-5-ylidene)iridium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 12112-67-3
bis(1,5-cyclooctadiene)diiridium(I) dichloride

: 201230-82-2
carbon monoxide

: 1263862-40-3
3-methyl-1,4-bis(2,4,6-trimethylphenyl)-1H-1,2,3-triazolium tetrafluoroborate

: 1370328-81-6
chlorodicarbonyl(3-methyl-1,4-bis(2,4,6-trimethylphenyl)-1,2,3-triazol-5-ylidene)iridium(I)

Guidance literature:: With (CH₃)3COK; In not given; C2HN3(Me)(Mes)2BF4 treated with tBuOK, (IrCl(cod))2 added, mixt. treatedwith excess of CO; G. Guisado-Barrios et al., Angew. Chem, Int. Ed. 201 0, 49, 4759-4762; elem. anal.;
DOI:10.1002/ejic.201101383