(S)-(-)-[4-benzyloxy-3-(tert-butyldimethylsilyloxy)butane]-1-sulfonylbenzene

Base Information

Chemical Name:(S)-(-)-[4-benzyloxy-3-(tert-butyldimethylsilyloxy)butane]-1-sulfonylbenzene
CAS No.:858666-71-4
Molecular Formula:C₂₃H₃₄O₄SSi
Molecular Weight:434.672
Hs Code.:

Synonyms:(S)-(-)-[4-benzyloxy-3-(tert-butyldimethylsilyloxy)butane]-1-sulfonylbenzene

Suppliers and Price of (S)-(-)-[4-benzyloxy-3-(tert-butyldimethylsilyloxy)butane]-1-sulfonylbenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (S)-(-)-[4-benzyloxy-3-(tert-butyldimethylsilyloxy)butane]-1-sulfonylbenzene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (S)-(-)-[4-benzyloxy-3-(tert-butyldimethylsilyloxy)butane]-1-sulfonylbenzene

There total 4 articles about (S)-(-)-[4-benzyloxy-3-(tert-butyldimethylsilyloxy)butane]-1-sulfonylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 3112-85-4
methylphenylsulfonate

: 69739-34-0
t-butyldimethylsiyl triflate

: 2930-05-4,14618-80-5,89616-40-0,16495-13-9
(S)-benzyl glycidyl ether

: 858666-71-4
(S)-(-)-[4-benzyloxy-3-(tert-butyldimethylsilyloxy)butane]-1-sulfonylbenzene

Guidance literature:: methylphenylsulfonate; (S)-benzyl glycidyl ether; With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; In tetrahydrofuran;

t-butyldimethylsiyl triflate; With 2,6-dimethylpyridine; In tetrahydrofuran;
DOI:10.1021/ol0507975

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 404914-43-8
(S)-4-Benzenesulfonyl-1-benzyloxy-butan-2-ol

: 858666-71-4
(S)-(-)-[4-benzyloxy-3-(tert-butyldimethylsilyloxy)butane]-1-sulfonylbenzene

Guidance literature:: With 2,6-dimethylpyridine; In tetrahydrofuran; hexane; at 0 ℃; for 2.5h;
DOI:10.1039/b600951d

Reference yield:

: 3112-85-4
methylphenylsulfonate

: 858666-71-4
(S)-(-)-[4-benzyloxy-3-(tert-butyldimethylsilyloxy)butane]-1-sulfonylbenzene

Guidance literature:: Multi-step reaction with 2 steps

1.1: BuLi / tetrahydrofuran; hexane / 0.67 h / -78 - 20 °C

1.2: hexamethylphosphoramide / tetrahydrofuran; hexane / 1.5 h

2.1: 0.58 g / 2,6-lutidine / tetrahydrofuran; hexane / 2.5 h / 0 °C

With 2,6-dimethylpyridine; n-butyllithium; In tetrahydrofuran; hexane;
DOI:10.1039/b600951d