Dimethyl (2S,3R,4R,5S)-2-<(9-phenyl-9-fluorenyl)amino>-3,4,5-trihydroxy-3,4-O-isopropylideneadipate

Base Information

Chemical Name:Dimethyl (2S,3R,4R,5S)-2-<(9-phenyl-9-fluorenyl)amino>-3,4,5-trihydroxy-3,4-O-isopropylideneadipate
CAS No.:154494-80-1
Molecular Formula:C₃₀H₃₁NO₇
Molecular Weight:517.579
Hs Code.:

Synonyms:Dimethyl (2S,3R,4R,5S)-2-<(9-phenyl-9-fluorenyl)amino>-3,4,5-trihydroxy-3,4-O-isopropylideneadipate

Suppliers and Price of Dimethyl (2S,3R,4R,5S)-2-<(9-phenyl-9-fluorenyl)amino>-3,4,5-trihydroxy-3,4-O-isopropylideneadipate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Dimethyl (2S,3R,4R,5S)-2-<(9-phenyl-9-fluorenyl)amino>-3,4,5-trihydroxy-3,4-O-isopropylideneadipate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Dimethyl (2S,3R,4R,5S)-2-<(9-phenyl-9-fluorenyl)amino>-3,4,5-trihydroxy-3,4-O-isopropylideneadipate

There total 3 articles about Dimethyl (2S,3R,4R,5S)-2-<(9-phenyl-9-fluorenyl)amino>-3,4,5-trihydroxy-3,4-O-isopropylideneadipate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 1054653-92-7
(S)-Hydroxy-{(4R,5R)-5-[(S)-methoxycarbonyl-(9-phenyl-9H-fluoren-9-ylamino)-methyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-acetic acid

: 74-88-4
methyl iodide

: 154494-80-1
Dimethyl (2S,3R,4R,5S)-2-<(9-phenyl-9-fluorenyl)amino>-3,4,5-trihydroxy-3,4-O-isopropylideneadipate

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; for 12h; Ambient temperature;
DOI:10.1021/jo00081a019

Reference yield:

: 133473-09-3
methyl 2-[(9-phenylfluoren-9-yl)amino]-2-deoxy-3,4:5,6-di-O-isopropylidene-D-mannonate

: 154494-80-1
Dimethyl (2S,3R,4R,5S)-2-<(9-phenyl-9-fluorenyl)amino>-3,4,5-trihydroxy-3,4-O-isopropylideneadipate

Guidance literature:: Multi-step reaction with 3 steps

1: 86 percent / aq. HCl / diethyl ether / 3 h / 0 °C

2: 60 percent / O₂ / Pt / H₂O; ethyl acetate; propan-2-ol / 40 °C

3: 98 percent / K₂CO₃ / dimethylformamide / 12 h / Ambient temperature

With hydrogenchloride; oxygen; potassium carbonate; platinum; In diethyl ether; water; ethyl acetate; N,N-dimethyl-formamide; isopropyl alcohol;
DOI:10.1021/jo00081a019

Reference yield:

: 154494-79-8
methyl 2-deoxy-3,4-O-isopropylidene-2-[(9-phenyl-9-fluorenyl)-amino]-D-mannonate

: 154494-80-1
Dimethyl (2S,3R,4R,5S)-2-<(9-phenyl-9-fluorenyl)amino>-3,4,5-trihydroxy-3,4-O-isopropylideneadipate

Guidance literature:: Multi-step reaction with 2 steps

1: 60 percent / O₂ / Pt / H₂O; ethyl acetate; propan-2-ol / 40 °C

2: 98 percent / K₂CO₃ / dimethylformamide / 12 h / Ambient temperature

With oxygen; potassium carbonate; platinum; In water; ethyl acetate; N,N-dimethyl-formamide; isopropyl alcohol;
DOI:10.1021/jo00081a019