dihydridobis(methanol)bis(triphenylphosphine)iridium(III) tetrafluoroborate

Base Information

Chemical Name:dihydridobis(methanol)bis(triphenylphosphine)iridium(III) tetrafluoroborate
CAS No.:83705-82-2
Molecular Formula:BF₄*C₃₈H₄₀IrO₂P₂
Molecular Weight:869.707
Hs Code.:

Synonyms:dihydridobis(methanol)bis(triphenylphosphine)iridium(III) tetrafluoroborate

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Chemical Property of dihydridobis(methanol)bis(triphenylphosphine)iridium(III) tetrafluoroborate

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Technology Process of dihydridobis(methanol)bis(triphenylphosphine)iridium(III) tetrafluoroborate

There total 2 articles about dihydridobis(methanol)bis(triphenylphosphine)iridium(III) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 38834-40-1
[Ir(1,5-COD)(P(C₆H₅)3)2]BF₄

: 83705-82-2
dihydridobis(methanol)bis(triphenylphosphine)iridium(III) tetrafluoroborate

Guidance literature:: With methanol; hydrogen; In methanol; Ir-complex suspd. in MeOH, H2 bubbled gently through soln. for 10 min at 0°C, Et2O added under H2 stream; recrystd. from CH2Cl2-Et2O; elem. anal.;
DOI:10.1021/ja00389a018

Reference yield:

: 67969-82-8
tetrafluoroboric acid diethyl ether

: 53470-69-2
pentahydridobis(triphenylphosphine)iridium(III)

: 83705-82-2
IrH₂(OHCH₃)2(P(C₆H₅)3)2⁽¹⁺⁾*BF₄^(1-)=IrH₂(CH₃OH)2(P(C₆H₅)3)2BF₄

Guidance literature:: With methanol; In methanol; byproducts: H2; stirred for 30 min at room temp. under Ar, excess of HBF4; solvent was removed in vac., MeOH and Et2O added, filtered, washed with Et2O, dried, recrystd. from CH2Cl2/Et2O;