5,10,15,20-tetra(p-tolyl)porphyrinato-rhodium(III)-p-fluorophenyl

Base Information

• Chemical Name: 5,10,15,20-tetra(p-tolyl)porphyrinato-rhodium(III)-p-fluorophenyl
• CAS No.: 1391996-60-3
• Molecular Formula: C₅₄H₄₀FN₄Rh
• Molecular Weight: 866.842
• Mol file: 1391996-60-3.mol

Synonyms:5,10,15,20-tetra(p-tolyl)porphyrinato-rhodium(III)-p-fluorophenyl

Chemical Property of 5,10,15,20-tetra(p-tolyl)porphyrinato-rhodium(III)-p-fluorophenyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15,20-tetra(p-tolyl)porphyrinato-rhodium(III)-p-fluorophenyl

There total 4 articles about 5,10,15,20-tetra(p-tolyl)porphyrinato-rhodium(III)-p-fluorophenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

rhodium(III) tetrakis(4-tolyl)porphyrin chloride (205259-72-9) + 1-Chloro-4-fluorobenzene (352-33-0) → Rh(tetra-p-tolylporphyrinato)(4-chlorophenyl) (1391996-54-5) + 5,10,15,20-tetra(p-tolyl)porphyrinato-rhodium(III)-p-fluorophenyl (1391996-60-3)

Guidance literature:

With potassium hydroxide; at 120 ℃; for 24h; Solvent; Temperature; Inert atmosphere;

DOI:10.1016/j.jorganchem.2015.05.039

Reference yield: 63.0%

rhodium(III) tetrakis(4-tolyl)porphyrin chloride (205259-72-9) + 1-Chloro-4-fluorobenzene (352-33-0) → 5,10,15,20-tetra(p-tolyl)porphyrinato-rhodium(III)-p-fluorophenyl (1391996-60-3)

Guidance literature:

With potassium hydroxide; at 200 ℃; for 24h; Inert atmosphere;

DOI:10.1016/j.jorganchem.2015.05.039

Reference yield: 60.0%

rhodium(III) tetrakis(4-tolyl)porphyrin chloride (205259-72-9) + 1-Bromo-4-fluorobenzene (460-00-4) → 5,10,15,20-tetra(p-tolyl)porphyrinato-rhodium(III)-p-fluorophenyl (1391996-60-3)

Guidance literature:

With potassium carbonate; tert-butyl alcohol; In benzene; at 120 ℃; for 8h; Inert atmosphere; Darkness;

DOI:10.1021/om300441p

upstream raw materials:

rhodium(III) tetrakis(4-tolyl)porphyrin chloride

1-Bromo-4-fluorobenzene

bromobenzene

1-Chloro-4-fluorobenzene