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1391996-54-5

Rh(tetra-p-tolylporphyrinato)(4-chlorophenyl) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1391996-54-5 Structure

  • Basic information

    1. Product Name: Rh(tetra-p-tolylporphyrinato)(4-chlorophenyl)
    2. Synonyms: Rh(tetra-p-tolylporphyrinato)(4-chlorophenyl)
    3. CAS NO:1391996-54-5
    4. Molecular Formula:
    5. Molecular Weight: 883.297
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1391996-54-5.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Rh(tetra-p-tolylporphyrinato)(4-chlorophenyl)(CAS DataBase Reference)
    10. NIST Chemistry Reference: Rh(tetra-p-tolylporphyrinato)(4-chlorophenyl)(1391996-54-5)
    11. EPA Substance Registry System: Rh(tetra-p-tolylporphyrinato)(4-chlorophenyl)(1391996-54-5)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1391996-54-5(Hazardous Substances Data)

1391996-54-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1391996-54-5 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,3,9,1,9,9 and 6 respectively; the second part has 2 digits, 5 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 1391996-54:
(9*1)+(8*3)+(7*9)+(6*1)+(5*9)+(4*9)+(3*6)+(2*5)+(1*4)=215
215 % 10 = 5
So 1391996-54-5 is a valid CAS Registry Number.

1391996-54-5Downstream Products

1391996-54-5Relevant articles and documents

Aryl carbon-chlorine (Ar-Cl) and aryl carbon-fluorine (Ar-F) bond cleavages by rhodium porphyrins

Qian, Ying Ying,Lee, Man Ho,Yang, Wu,Chan, Kin Shing

, p. 82 - 89 (2015/06/08)

Aryl carbon-chlorine (Ar-Cl) bond cleavage has been achieved with rhodium(III) tetrakis-4-tolylporphyrin chloride (Rh(ttp)Cl) to give Rh(ttp)Ar. For 4-chlorofluorobenzene, the aryl carbon-fluorine (Ar-F) bond cleavage competes with the Ar-Cl bond cleavage. Mechanistic investigations show that the Ar-Cl bond cleavage goes through metalloradical ipso-substitution mechanism, while the Ar-F bond cleavage goes through nucleophilic aromatic substitution. The selectivity of the Ar-F or Ar-Cl bond cleavage can be controlled by tuning the temperature and substrate concentration.

Base-promoted aryl carbon-iodine and carbon-bromine bond cleavage with rhodium porphyrin complexes: Scope and mechanism

Qian, Ying Ying,Chan, Kin Shing

, p. 5452 - 5462 (2012/11/13)

Base-promoted aryl carbon-iodine and carbon-bromine bond (Ar-X, X = I, Br) cleavage by rhodium porphyrin complexes was achieved to give the rhodium(III) porphyrin aryls Rh(ttp)Ar (ttp = tetra-p-tolylporphyrinato dianion). Mechanistic studies showed that RhII2(ttp)2 is the intermediate for Ar-X (X = I, Br) cleavage. The Ar-X cleavage process goes through a rhodium(II) porphyrin radical mediated ipso-substitution mechanism.

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