(E)-(4S,5R,6S,8S,9R)-9-(2,5-Dimethoxy-3-nitro-phenyl)-5,6,9-trimethoxy-2,4,8-trimethyl-non-2-enoic acid ethyl ester

Base Information

Chemical Name:(E)-(4S,5R,6S,8S,9R)-9-(2,5-Dimethoxy-3-nitro-phenyl)-5,6,9-trimethoxy-2,4,8-trimethyl-non-2-enoic acid ethyl ester
CAS No.:170707-55-8
Molecular Formula:C₂₅H₃₉NO₉
Molecular Weight:497.586
Hs Code.:

Synonyms:(E)-(4S,5R,6S,8S,9R)-9-(2,5-Dimethoxy-3-nitro-phenyl)-5,6,9-trimethoxy-2,4,8-trimethyl-non-2-enoic acid ethyl ester

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Chemical Property of (E)-(4S,5R,6S,8S,9R)-9-(2,5-Dimethoxy-3-nitro-phenyl)-5,6,9-trimethoxy-2,4,8-trimethyl-non-2-enoic acid ethyl ester

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Technology Process of (E)-(4S,5R,6S,8S,9R)-9-(2,5-Dimethoxy-3-nitro-phenyl)-5,6,9-trimethoxy-2,4,8-trimethyl-non-2-enoic acid ethyl ester

There total 25 articles about (E)-(4S,5R,6S,8S,9R)-9-(2,5-Dimethoxy-3-nitro-phenyl)-5,6,9-trimethoxy-2,4,8-trimethyl-non-2-enoic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 170707-54-7
(2R,3R,4S,6S,7R)-7-(2,5-dimethoxy-3-nitrophenyl)-3,4,7-trimethoxy-2,6-dimethylheptanal

: 21382-82-1
(carbethoxyethylidene)triphenylphosphorane

: 170707-55-8
(E)-(4S,5R,6S,8S,9R)-9-(2,5-Dimethoxy-3-nitro-phenyl)-5,6,9-trimethoxy-2,4,8-trimethyl-non-2-enoic acid ethyl ester

Guidance literature:: In toluene; Heating;
DOI:10.1021/ja00147a027 DOI:10.1021/ja974318b

Reference yield:

: 170901-52-7
(2R,3S,5S,6R)-2-Benzyloxy-6-(2,5-dimethoxy-3-nitro-phenyl)-6-methoxy-5-methyl-hexane-1,3-diol

: 170707-55-8
(E)-(4S,5R,6S,8S,9R)-9-(2,5-Dimethoxy-3-nitro-phenyl)-5,6,9-trimethoxy-2,4,8-trimethyl-non-2-enoic acid ethyl ester

Guidance literature:: Multi-step reaction with 8 steps

1.1: 98 percent / TBAF

2.1: BCl₃*SMe₂

2.2: NaIO₄

3.1: TMSOTf

4.1: OsO₄; NMO

5.1: Pb(OAc)4; K₂CO₃

6.1: 78 percent / toluene

With lead(IV) acetate; osmium(VIII) oxide; N-methyl-2-indolinone; trimethylsilyl trifluoromethanesulfonate; boron trichloride - methyl sulfide complex; tetrabutyl ammonium fluoride; potassium carbonate; In toluene; 8.1: Wittig reaction;
DOI:10.1021/ol036092p

Reference yield:

: 170707-50-3
(2R,3S,5S,6R)-2-Benzyloxy-6-(2,5-dimethoxy-3-nitro-phenyl)-3,6-dimethoxy-5-methyl-hexan-1-ol

: 170707-55-8
(E)-(4S,5R,6S,8S,9R)-9-(2,5-Dimethoxy-3-nitro-phenyl)-5,6,9-trimethoxy-2,4,8-trimethyl-non-2-enoic acid ethyl ester

Guidance literature:: Multi-step reaction with 5 steps

1.1: BCl₃*SMe₂

1.2: NaIO₄

2.1: TMSOTf

3.1: OsO₄; NMO

4.1: Pb(OAc)4; K₂CO₃

5.1: 78 percent / toluene

With lead(IV) acetate; osmium(VIII) oxide; N-methyl-2-indolinone; trimethylsilyl trifluoromethanesulfonate; boron trichloride - methyl sulfide complex; potassium carbonate; In toluene; 5.1: Wittig reaction;
DOI:10.1021/ol036092p